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相关概念视频

Polymers02:34

Polymers

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The word polymer is derived from the Greek words “poly” which means “many” and “mer” which means “parts”. Polymers are long chains of molecules composed of repeating units of smaller molecules, known as monomers. They either occur naturally, such as DNA and proteins, or can be constructed synthetically, like plastics. They have varied structural characteristics, such as linear chains, branched chains, or complex networks, that contribute to the...
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DNA replication involves the separation of the two strands of the double helix, with each strand serving as a template from which the new complementary strand is copied.  After replication, each double-stranded DNA includes one parental or “old” strand and one “new” strand. This is known as semiconservative replication. The resulting DNA molecules have the same sequence and are divided equally into the two daughter cells.
Replication in Prokaryotes
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Dynamic Equilibrium02:20

Dynamic Equilibrium

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A reversible chemical reaction represents a chemical process that proceeds in both forward (left to right) and reverse (right to left) directions. When the rates of the forward and reverse reactions are equal, the concentrations of the reactant and product species remain constant over time and the system is at equilibrium. A special double arrow is used to emphasize the reversible nature of the reaction. The relative concentrations of reactants and products in equilibrium systems vary greatly;...
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Polymers are classified as linear or branched on the basis of their chain architecture. The polymer chains in linear polymers have a long chain-like structure with minimal to no branching at all. Even if a polymer features large substituent groups on the monomer, which appear as branches to the skeleton, it is not considered a branched polymer. A branched polymer contains secondary polymer chains that arise from the main polymer chain. The branching occurs when the polymer growth shifts from...
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Unlike ionic or small covalent molecules, polymers do not form crystalline solids due to the diffusion limitations of their long-chain structures. However, polymers contain microscopic crystalline domains separated by amorphous domains.
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动态和响应性DNA类聚合物

Sudheendran Mavila1, Brady T Worrell1, Heidi R Culver1

  • 1Department of Chemical and Biological Engineering , University of Colorado-Boulder , Boulder , Colorado 80309 , United States.

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概括
此摘要是机器生成的。

研究人员合成了用于环开聚合 (ROP) 的新型硫黄素单体. 这些聚合物允许通过醇-醇交换进行动态重新排列,从而实现受控的聚合物合成.

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科学领域:

  • 聚合物化学
  • 有机合成
  • 材料科学

背景情况:

  • 核酸类比在各种应用中至关重要.
  • 环开聚合 (ROP) 是一种多功能聚合技术.
  • 控制的聚合物合成仍然是一个重大挑战.

研究的目的:

  • 开发可模仿自然核酸的新型乳酸单体.
  • 研究这些单体的环开聚合 (ROP).
  • 探索由此产生的聚合物的动态重排能力,以实现受控合成.

主要方法:

  • 为了模仿核酸而设计的酸单体的合成.
  • 使用这些单体进行强大的环开聚合 (ROP).
  • 通过 thiol-thioester 交换,包括去聚合和聚合物凝聚的动态聚合物重组的演示.

主要成果:

  • 成功合成了酸盐单体.
  • 强大的环开聚合 (ROP) 产生具有基功能组的聚合物.
  • 动态聚合物重组的可行性,包括不同特性聚合物的脱聚合和合并.

结论:

  • 开发的酸盐单体和ROP工艺可以制造动态聚合物.
  • -交换提供了聚合物重组和受控合成的机制.
  • 这项工作为实现顺序控制聚合物的常规合成奠定了基础.