和土化物驱动的N2激活和转化在Mn化剂上
Fei Chang1,2, Yeqin Guan1,2, Xinghua Chang3
1Dalian National Laboratory for Clean Energy , Dalian Institute of Chemical Physics, Chinese Academy of Sciences , Dalian 116023 , P. R. China.
Journal of the American Chemical Society
|October 24, 2018
概括
和土金属化物显著增加化物
科学领域:
- 催化剂
- 材料科学
- 化学工程
背景情况:
- 早期的3D过渡金属通常是较差的催化剂,因为它们与反应物有很强的亲和力.
- 在典型条件下,化对氨合成具有微不足道的活性.
研究的目的:
- 研究和土金属化物 (AHs) 对化物的催化促进作用,以合成氨.
- 了解催化活性增强背后的机制.
主要方法:
- 通过各种AH促进的化物的实验合成和表征.
- 在不同条件下测试氨合成反应.
- 在现场进行机制研究以阐明AHs的作用.
主要成果:
- 酸盐通过数量级促进化物活性,其促进顺序为 BaH2 > LiH > KH > CaH2 > NaH.
- 氧化可以从化中提取,从而增加2的激活和氨的产生.
- Mn-LiH系统的活性阶段和动力学对反应条件高度敏感.
结论:
- 酸,特别是负电荷的酸,是酸催化剂的有效促进剂.
- 这项工作提出了用于氨合成和其他化学过程的早期过渡金属催化剂的设计策略.
相关概念视频
Alkali Metals
24.6K
Group 1 elements are soft and shiny metallic solids. They are malleable, ductile, and good conductors of heat and electricity. The melting points of the alkali metals are unusually low for metals and decrease going down the group, while the density increases going down the group with the exception of potassium (Table 1).
Table 1: Properties of the alkali metals
Table 1: Properties of the alkali metals
24.6K
Esters to Alcohols: Hydride Reductions
4.8K
Esters are reduced to primary alcohols when treated with a strong reducing agent like lithium aluminum hydride. The reaction requires two equivalents of the reducing agent and proceeds via an aldehyde intermediate.
Lithium aluminum hydride is a source of hydride ions and functions as a nucleophile. The mechanism proceeds in three steps. Firstly, the nucleophilic hydride ion attacks the carbonyl carbon of the ester to form a tetrahedral intermediate. Subsequently, the carbonyl group re-forms,...
Lithium aluminum hydride is a source of hydride ions and functions as a nucleophile. The mechanism proceeds in three steps. Firstly, the nucleophilic hydride ion attacks the carbonyl carbon of the ester to form a tetrahedral intermediate. Subsequently, the carbonyl group re-forms,...
4.8K
Conditions on Early Earth
101.5K
Around 4 billion years ago, oceans began to condense on earth while volcanic eruptions released nitrogen, carbon dioxide, methane, ammonia, and hydrogen into the primordial atmosphere. However, organisms with the characteristics of life were not initially present on earth. Scientists have used experimentation to determine how organisms evolved that could grow, reproduce, and maintain an internal environment.
101.5K
Alkali Aggregate Reaction in Concrete
541
The alkali-aggregate reaction in concrete involves natural siliceous minerals in aggregates reacting with alkaline hydroxides derived from cement alkalis. This reaction forms an alkali-silica gel that absorbs water, swells, and increases in volume, which is confined by the surrounding cement paste, creating internal pressures that crack and disrupt the concrete. The extent of expansion and damage can be partly attributed to the alkali-silica reaction's osmotic hydraulic pressure and the...
541
Bacterial Transformation
59.9K
In 1928, bacteriologist Frederick Griffith worked on a vaccine for pneumonia, which is caused by Streptococcus pneumoniae bacteria. Griffith studied two pneumonia strains in mice: one pathogenic and one non-pathogenic. Only the pathogenic strain killed host mice.
Griffith made an unexpected discovery when he killed the pathogenic strain and mixed its remains with the live, non-pathogenic strain. Not only did the mixture kill host mice, but it also contained living pathogenic bacteria that...
Griffith made an unexpected discovery when he killed the pathogenic strain and mixed its remains with the live, non-pathogenic strain. Not only did the mixture kill host mice, but it also contained living pathogenic bacteria that...
59.9K
Acceleration due to Gravity on Earth
12.1K
According to Newton's law of gravitation, the gravitational force on a body is proportional to its mass. According to Newton's second law of motion, the acceleration produced by an external force is inversely proportional to the force. Hence, the acceleration of an object under an external force of gravitation is independent of its mass.
The acceleration of an object close to the Earth, because of the Earth's gravitational pull, is called the acceleration due to gravity. It is...
The acceleration of an object close to the Earth, because of the Earth's gravitational pull, is called the acceleration due to gravity. It is...
12.1K


