超快速宽带充电采集从清洁石墨烯/CH3NH3PbI3接口
Hao Hong1, Jincan Zhang2, Jin Zhang3
1State Key Laboratory for Mesoscopic Physics, Collaborative Innovation Centre of Quantum Matter, School of Physics , Peking University , Beijing 100871 , China.
Journal of the American Chemical Society
|October 25, 2018
概括
研究人员使用干净的石墨烯/矿接口实现了超高速宽带电荷收集. 这一光电技术的突破有望提高光伏设备的电流和能量转换效率.
科学领域:
- 材料科学
- 光电子产品
- 太阳能发电
背景情况:
- 对于光电子和光伏设备来说,有效的电荷收集至关重要.
- 超高速和宽带充电采集是提高电流和能源转换效率的关键.
研究的目的:
- 证明在干净的石墨烯/矿接口上同时进行超快速和宽带的电荷收集.
- 调查这种新型接口的电荷收集动态.
主要方法:
- 在石墨烯上直接生长石,以确保干净的接口.
- 可调节的双色探测谱.
- 时间分辨率光发光谱.
- 时间依赖密度函数理论计算.
主要成果:
- 实现带边光载体的超快速 (∼100 fs) 宽带电荷收集.
- 已证明近单位电流采集效率 (∼99%).
- 石墨烯在≤50 fs中提取热载体,超过矿的内在冷却速度.
- 突出了石墨烯独特的迪拉克线性带结构,用于高效的热载体提取.
结论:
- 一个干净的石墨烯/矿接口可以同时采集超快速和宽带的电荷.
- 由于其特性和迪拉克带结构,石墨烯充当了理想的电荷收集层.
- 这种方法为高效光电子和光伏设备提供了潜力,可能会超过Shockley-Queisser极限.
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