一个晶体聚胺多孔的有机框架,用于对乙烯进行选择性吸附
Lingchang Jiang1, Yuyang Tian2, Tu Sun3
1State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry , Jilin University , Changchun 130012 , China.
Journal of the American Chemical Society
|October 27, 2018
概括
一种新的多孔材料PAF-110选择性地通过乙烯吸附乙烯,这是生产纯乙烯的关键步骤. 这种稳定的材料为石化行业提供了增强的分离能力.
科学领域:
- 材料科学
- 化学工程
- 分离科学
背景情况:
- 乙烯杂质阻碍了乙烯的聚合,需要有效的分离方法.
- 目前的分离技术在实现高纯度和效率方面面临挑战.
研究的目的:
- 合成和描述一种用于选择性乙吸附的新型多孔有机材料.
- 研究该材料在从乙烯分离中的稳定性和性能.
主要方法:
- 通过纳二化和三4-氨基胺的模化合成PAF-110.
- 使用热重力学分析和粉末X射线衍射进行表征.
- 在不同温度和压力下进行气体吸附研究.
主要成果:
- PAF-110具有很高的热和结构稳定性.
- 这种材料在273K时的乙烯吸附能力是乙烯的2倍.
- 在298K时观察到适度的乙选择性 (3.9), 归因于静电相互作用.
结论:
- PAF-110是第一个在乙烯上表现出选择性乙烯吸附的晶体多孔有机材料.
- 这些发现为石油化工行业的关键气体分离设计先进的多孔材料提供了洞察力.
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