循环和双循环的单分子导电的巨大变化
Haixing Li, Marc H Garner1, Zhichun Shangguan2
1Nano-Science Center and Department of Chemistry , University of Copenhagen , Universitetsparken 5 , 2100 Copenhagen Ø , Denmark.
Journal of the American Chemical Society
|October 30, 2018
概括
由西兰制成的分子电线的导电性取决于它们的3D形状. 研究人员研究了循环和双循环,发现特定的角度控制电流,使得定制的分子电子设计成为可能.
科学领域:
- 材料科学
- 有机化学
- 纳米技术
背景情况:
- 线性西兰通过西格玛结合表现出高效的分子线性质.
- 分子构成对西兰单分子导电性的影响尚不清楚.
研究的目的:
- 研究循环和双循环的结构导电关系.
- 探索分子构造如何影响单分子导电.
主要方法:
- 四个系列的功能化循环和双循环的合成.
- 单分子导电性的电测量.
- 锡兰结构和电子性质的理论描述.
主要成果:
- 观察到单分子导电的异常变化.
- 根据共同的长度依赖来确定相对导电.
- 被发现的导电性主要由单一路径控制,并由二面角控制.
结论:
- 在西格玛结合的西兰中单分子导电性对分子构造高度敏感.
- 分子设计通过构造调节来系统地控制导电量.
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