一个独特的对:Ag40和Ag46纳米集群具有相同的表面,但结构与属性相关的核心不同
Jinsong Chai1, Sha Yang1, Ying Lv1
1Department of Chemistry and Centre for Atomic Engineering of Advanced Materials, Anhui Province Key Laboratory of Chemistry for Inorganic/Organic Hybrid Functionalized Materials , Anhui University , Hefei , Anhui 230601 , China.
Journal of the American Chemical Society
|November 6, 2018
概括
这项研究合成了两个具有独特核心结构的新银纳米集群. 这些发现表明,核心包装显著影响这些金属纳米集群的光学特性.
科学领域:
- 材料科学
- 纳米技术
- 物理化学
背景情况:
- 了解纳米集群的光学特性对于基础研究至关重要.
- 由于其独特的光学特征, 银纳米集群很有趣.
研究的目的:
- 合成和特征两个新的银纳米集群与不同的核心结构,但一个共同的外.
- 研究核心结构对银纳米集群的光学吸收特性的影响.
主要方法:
- 两个银纳米集群的合成:[Ag40[2,4-DMBT]24[PPh3]8]和[Ag46[2,5-DMBT]24[PPh3]8]2+.
- 对光学吸收特性进行实验研究.
- 对核心外结构及其对电子轨道的影响的分析.
主要成果:
- 成功合成了两个不同的银纳米集群与共享的保护.
- 在Ag40纳米集群中观察到一个简单的立方Ag8核心,这是金属材料的首次.
- 证明核心包装模式 (紧与松散) 影响边界轨道退化和光学吸收.
结论:
- 核心包装模式是金属纳米集群光学特性的一个重要决定因素.
- 合成的纳米集群具有受控的晶体相,显示出未来应用的潜力.
相关概念视频
The Nucleosome Core Particle
14.5K
Nucleosomes are the DNA-histone complex, where the DNA strand is wound around the histone core. The histone core is an octamer containing two copies of H2A, H2B, H3, and H4 histone proteins.
The paradox
Nucleosomes, paradoxically, perform two opposite functions simultaneously. On the one hand, their main responsibility is to protect the delicate DNA strands from physical damage and help achieve a higher compaction ratio. While on the other hand, they must allow polymerase enzymes to access DNA...
The paradox
Nucleosomes, paradoxically, perform two opposite functions simultaneously. On the one hand, their main responsibility is to protect the delicate DNA strands from physical damage and help achieve a higher compaction ratio. While on the other hand, they must allow polymerase enzymes to access DNA...
14.5K
Other Unique Bacteria
440
Magnetic bacteria exhibit a directed movement called magnetotaxis, driven by structures called magnetosomes. These magnetosomes consist of chains of magnetic particles made of either magnetite (Fe₃O₄) or greigite (Fe₃S₄) and are organized in a linear conformation by a protein scaffold within invaginations of the cell membrane. The bacteria align along the north–south magnetic field lines, much like a compass needle. They are typically microaerophilic or anaerobic...
440
Structural Properties and Dimensions of Lumber
402
Wood's structural properties derive from fibers aligned along the tree's length, contributing significantly to its mechanical strength. Wood exhibits up to twenty times greater tensile strength along these fibers compared to across them, and generally shows better performance under compression than tension. The length of fibers varies, with hardwoods having fibers around one twenty-fifth inch long and softwoods ranging from one-eighth to one-third inch.
The strength characteristics of...
The strength characteristics of...
402
Structure and Physical Properties of Alkynes
13.3K
Introduction:
In nature, compounds containing both carbon and hydrogen are known as "hydrocarbons". Aliphatic hydrocarbons are compounds whose molecules contain saturated single bonds (i.e., alkanes) or unsaturated double or triple bonds. Alkenes contain carbon–carbon double bonds and have a structural formula CnH2n. Unsaturated hydrocarbons containing carbon–carbon triple bonds are called "alkynes" and are structurally represented by the formula CnH2n-2.
The...
In nature, compounds containing both carbon and hydrogen are known as "hydrocarbons". Aliphatic hydrocarbons are compounds whose molecules contain saturated single bonds (i.e., alkanes) or unsaturated double or triple bonds. Alkenes contain carbon–carbon double bonds and have a structural formula CnH2n. Unsaturated hydrocarbons containing carbon–carbon triple bonds are called "alkynes" and are structurally represented by the formula CnH2n-2.
The...
13.3K
Second Uniqueness Theorem
2.6K
Consider a region consisting of several individual conductors with a definite charge density in the region between these conductors. The second uniqueness theorem states that if the total charge on each conductor and the charge density in the in-between region are known, then the electric field can be uniquely determined.
In contrast, consider that the electric field is non-unique and apply Gauss's law in divergence form in the region between the conductors and the integral form to the surface...
In contrast, consider that the electric field is non-unique and apply Gauss's law in divergence form in the region between the conductors and the integral form to the surface...
2.6K
Correlations
35.9K
Correlation means that there is a relationship between two or more variables (such as ice cream consumption and crime), but this relationship does not necessarily imply cause and effect. When two variables are correlated, it simply means that as one variable changes, so does the other. We can measure correlation by calculating a statistic known as a correlation coefficient. A correlation coefficient is a number from -1 to +1 that indicates the strength and direction of the relationship between...
35.9K


