在两种无孔多态和高表面积有孔相之间可逆切换的协调网络
Ai-Xin Zhu1,2, Qing-Yuan Yang2,3, Amrit Kumar2
1Faculty of Chemistry and Chemical Engineering , Yunnan Normal University , Kunming 650500 , China.
Journal of the American Chemical Society
|November 6, 2018
概括
一个新的金属有机框架,X-pcu-5-Zn,显示开放和关闭状态之间的可逆切换,使高二氧化碳储存. 这种材料
科学领域:
- 材料科学
- 化学学
- 纳米技术
背景情况:
- 金属有机框架 (MOF) 是气体储存的前景.
- 可切换的MOF可以动态控制多孔性.
- 了解MOF中的相位转换对于应用至关重要.
研究的目的:
- 合成和描述一个新的相互透的原始立方 (pcu) 网络,X-pcu-5-Zn.
- 调查X-pcu-5-Zn的可逆相切换行为.
- 探索X-pcu-5-Zn的气体吸附特性和潜在应用.
主要方法:
- 溶热合成的X-pcu-5-Zn.
- 气体吸附分析 (在195K时的二氧化碳吸收).
- 单晶X射线衍射用于多态的结构特征.
主要成果:
- 一个双重交互的pcu网络,X-pcu-5-Zn,被合成.
- X-pcu-5-Zn在开放式 (α) 和闭合式 (β,γ) 多态体之间呈现可逆切换.
- 通过F-IV型异热器,α形式显示高二氧化碳吸收率 (255 cm3/g).
- 通过激活带有二氧化碳的α形式来分离β多态,通过循环持续存在.
- 阶段变化以单晶到单晶的方式发生.
结论:
- X-pcu-5-Zn显示出高二氧化碳吸收和可逆转换的独特组合.
- 通过气体激活来分离新的多态体是前所未有的.
- 单晶到单晶相过渡有助于理解动态MOF的结构.
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