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从金属有机框架 (MOF) /聚合物复合物中快速选择性地提取微量黄金
Daniel T Sun1, Natalia Gasilova1, Shuliang Yang1
1Institute of Chemical Sciences and Engineering , École Polytechnique Fédérale de Lausanne (EPFL) , CH-1950 Sion , Switzerland.
Journal of the American Chemical Society
|November 6, 2018
概括
研究人员开发了一种新型的复合材料, 这项新技术可从电子废物和废水中提取高容量和快速的黄金.
科学领域:
- 材料科学
- 环境化学
- 纳米技术
背景情况:
- 越来越多的电子垃圾需要超越传统采矿的先进的黄金回收方法.
- 现有的技术缺乏从复杂的液态基质中提取超微量黄金的效率和选择性.
研究的目的:
- 设计和开发高度多孔的复合材料用于选择性黄金开采.
- 评估这些复合材料从各种水环境中回收黄金的性能.
主要方法:
- 使用金属有机框架 (MOF) 模板和氧化还原活性聚合物制造多孔复合材料.
- 从各种水类中测试特定复合物 (Fe-BTC/PpPDA) 的黄金提取效率和速率.
- 评估材料的容量,选择性和可循环利用性.
主要成果:
- 该Fe-BTC/PpPDA复合物从包括废水,海洋水和电子废物在内的复杂混合物中快速提取黄金 (仅需2分钟).
- 实现了934毫克黄金/克复合材料的特殊淘金能力.
- 这种材料具有很高的循环利用性,使其能够有效缩到23.9K的纯度.
结论:
- 开发的基于MOF的复合材料提供了超微量黄金回收的开创性解决方案.
- 这项技术为从电子废物和其他复杂来源回收黄金提供了可持续和高效的方法.
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