二维混合化矿:原则和承诺
Lingling Mao1, Constantinos C Stoumpos1, Mercouri G Kanatzidis1
1Department of Chemistry , Northwestern University , 2145 Sheridan Road , Evanston , Illinois 60208 , United States.
Journal of the American Chemical Society
|November 7, 2018
概括
二维 (2D) 化矿为光电子产品提供了增强的可调性和光物理性质. 它们的结构演变成为量子井, 允许对光学和介电性质进行精确控制,
科学领域:
- 材料科学
- 固态物理
- 纳米技术
背景情况:
- 混合化,特别是三维 (3D) 变种,如甲基化 (CH3NH3PbI3),在高性能光伏中显示出显著的希望.
- 降低维度的矿,特别是二维 (2D) 衍生物,代表了下一个前沿,为先进的应用提供了更高的可调性和优越的光物理特性.
研究的目的:
- 提供二维化矿从早期研究到目前的突出地位的历史视角.
- 根据其无机和有机成分分类二维化矿的多种结构类型.
- 突出结构-属性关系,使量子井的形成和对光电子属性的控制成为可能.
主要方法:
- 基于无机层修饰和有机阴离子多样性的二维化的结构分类.
- 分析合成操作和外部刺激 (温度,压力) 如何影响矿结构和量子井形成.
- 对控制介电和光学特征的结构属性相关性的审查.
主要成果:
- 2D化物矿表现出模块化结构,演变为结晶学定义的量子井 (QW).
- 这些QW的电子结构对特定的结构特征非常敏感.
- 这些特征可以用来精确调整QW的介电和光学特性.
结论:
- 2D化物矿是一种多功能半导体混合体,具有高性能光电子的特殊潜力.
- 了解它们的结构多样性和可调性是释放未来材料设计和技术进步的关键.
- 在展示基于二维矿的光电子设备方面取得了重大进展,为进一步的创新铺平了道路.
相关概念视频
The Uncertainty Principle
31.9K
Werner Heisenberg considered the limits of how accurately one can measure properties of an electron or other microscopic particles. He determined that there is a fundamental limit to how accurately one can measure both a particle’s position and its momentum simultaneously. The more accurate the measurement of the momentum of a particle is known, the less accurate the position at that time is known and vice versa. This is what is now called the Heisenberg uncertainty principle. He...
31.9K
Hybrid Zones
21.9K
Hybrid zones are narrow regions where two closely related species interact, mate, and produce hybrids. Relative to either parent species, hybrids may possess distinct phenotypic or genetic differences that impact their survival and reproductive success. The genetic variances introduced by hybridization influence species diversity and speciation processes within the hybrid zone.
21.9K
Hardy-Weinberg Principle
76.3K
Diploid organisms have two alleles of each gene, one from each parent, in their somatic cells. Therefore, each individual contributes two alleles to the gene pool of the population. The gene pool of a population is the sum of every allele of all genes within that population and has some degree of variation. Genetic variation is typically expressed as a relative frequency, which is the percentage of the total population that has a given allele, genotype or phenotype.
76.3K
The Pauli Exclusion Principle
59.3K
The arrangement of electrons in the orbitals of an atom is called its electron configuration. We describe an electron configuration with a symbol that contains three pieces of information:
59.3K
Alkyl Halides
20.0K
Structural Properties
Alkyl halides are halogen-substituted alkanes wherein one or more hydrogen atoms of an alkane is replaced by a halogen atom such as fluorine, chlorine, bromine, or iodine. The carbon atom in an alkyl halide is bonded to the halogen atom, which is sp3-hybridized and exhibits a tetrahedral shape.
Unlike alkyl halides, compounds in which a halogen atom is bonded to an sp2 -hybridized carbon atom of a carbon-carbon double bond (C=C) are called vinyl halides. Whereas aryl...
Alkyl halides are halogen-substituted alkanes wherein one or more hydrogen atoms of an alkane is replaced by a halogen atom such as fluorine, chlorine, bromine, or iodine. The carbon atom in an alkyl halide is bonded to the halogen atom, which is sp3-hybridized and exhibits a tetrahedral shape.
Unlike alkyl halides, compounds in which a halogen atom is bonded to an sp2 -hybridized carbon atom of a carbon-carbon double bond (C=C) are called vinyl halides. Whereas aryl...
20.0K
Dimensional Analysis
64.5K
Dimensional analysis, also known as the factor label method, is a versatile approach for mathematical operations. The main principle behind this approach is: the units of quantities must be subjected to the same mathematical operations as their associated numbers. This method can be applied to computations ranging from simple unit conversions to more complex and multi-step calculations involving several different quantities and their units.
Conversion Factors and Dimensional Analysis
The unit...
Conversion Factors and Dimensional Analysis
The unit...
64.5K


