金属替代对压力诱导的灵活的地质石化化框架的相变的影响
C Michael McGuirk1, Tomče Runčevski1,2, Julia Oktawiec1
1Department of Chemistry , University of California , Berkeley , California 94720 , United States.
Journal of the American Chemical Society
|November 8, 2018
概括
具有阶梯形吸附轮的金属有机框架可以有效地储存和分离气体. 灵活的焦化物模酸框架 (ZIF) 的化学调整改变了它们对压力反应的相变,影响了CO2和CH4吸附能力和压力.
科学领域:
- 材料科学
- 化学学
- 化学工程
背景情况:
- 具有阶梯形吸附等热体的金属有机框架 (MOF) 对气体储存和分离有价值.
- 了解这些MOF中压力诱导的相变对于优化它们的性能至关重要.
- 灵活的焦化物模酸框架 (ZIF) 为此类应用提供了可调节的特性.
研究的目的:
- 调查金属替代对等状ZIF的压力反应相变的影响.
- 阐明结构转换和气体吸附行为 (CO2和CH4) 之间的关系.
- 探索这些材料在气体储存,分离和内在热管理方面的潜力.
主要方法:
- 一系列异构ZIF (ZIF-7,ZIF-9,CdIF-13) 的合成和表征.
- 高压气体吸附测量 (CO2和CH4)
- 在现场进行结构特征,以监测相位过渡.
主要成果:
- ZIF-7 呈现出经过验证的CH4吸附阶段.
- 对于CO2和CH4吸附步骤,ZIF-9显示了类似的相位变化和转移的值压力.
- CdIF-13表现出明显的吸附行为,具有增加的容量,更高的值压力,以及单晶到单晶相变为孔隙相.
- 在气体吸附过程中,内热相变提供了内在的热管理.
结论:
- 柔性ZIF中的金属替代对压力响应相变和气体吸附性能产生重大影响.
- CdIF-13为气体应用提供了有前途的MOF,具有增强的容量和独特的相位过渡行为.
- 这些ZIF为开发具有内置热调节的高能效气体储存和分离的先进材料提供了一个平台.
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