超低载荷-燃料电池催化剂,来自意达酸框架
Lina Chong1, Jianguo Wen2, Joseph Kubal2,3
1Chemical Sciences and Engineering Division, Argonne National Laboratory, Lemont, IL 60439, USA.
概括
研究人员使用超低和基前体开发了新的电催化剂. 这些催化剂在燃料电池中具有高活性和稳定性,对于降低成本至关重要.
科学领域:
- 电化学
- 材料科学
- 催化剂
背景情况:
- 减少含量是降低燃料电池成本的关键.
- 开发高活性和稳定的电催化剂对于燃料电池的高效运行至关重要.
研究的目的:
- 创建具有超低负载的新型电催化剂以提高燃料电池性能.
- 研究-纳米颗粒和无PGM基底的协同效应.
主要方法:
- 作为前体使用或双金属-二氧化物模酸框架.
- 在没有PGM的基板上制备过的-核心外纳米颗粒.
- 使用计算建模来理解催化机制.
主要成果:
- 达到高氧降解反应 (ORR) 质量活动 (1.08 和 1.77 A mgPt-1).
- 在高电压和电流下在O2或空气下表现出极好的燃料电池性能.
- 在3万个电压周期后,催化剂保持了64%和15%的初始活性.
结论:
- 在Pt-Co纳米颗粒和无PGM位点之间的协同催化增强了ORR活性和耐久性.
- 这种方法为具有成本效益的燃料电池电催化剂提供了一个有希望的策略.
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