使用纳米相图的材料多态的指导合成
Xuetian Ma1, Adelaide M Nolan2, Shuo Zhang2
1The Woodruff School of Mechanical Engineering , Georgia Institute of Technology , 771 Ferst Drive , Atlanta , Georgia 30332 , United States.
Journal of the American Chemical Society
|November 14, 2018
概括
由于表面能量,纳米材料表现出独特的相位行为,使得可控合成的转移稳定相位. 这项研究使用先进技术揭示了纳米晶体的大小和表面依赖的多态性.
科学领域:
- 材料科学
- 纳米技术
- 固态化学
背景情况:
- 大量相图不足以预测纳米材料的合成.
- 表面能量显著影响纳米晶体的总能量和相位稳定性.
- 纳米材料可以表现出多态性,产生大量未观察到的转移稳定阶段.
研究的目的:
- 了解纳米材料多态性的理论和系统基础.
- 研究金属纳米晶体的尺寸和表面依赖相位行为.
- 开发一种用于合成超稳定纳米材料的预测方法.
主要方法:
- 使用金属作为研究多态的模型系统 (fcc和hcp阶段).
- 采用溶热反应对多态的选择性合成.
- 在现场应用同步射线衍射 (XRD) 和密度函数理论 (DFT) 计算.
主要成果:
- 在纳米晶体中100%选择调节fcc和hcp相.
- 揭示了纳米材料多态性中的尺寸和表面能量的关键作用.
- 建立了一个纳米相图来预测转移稳定的相位形成.
结论:
- 表面能量是纳米材料多态性的关键因素.
- 开发的纳米相图提供了材料合成的预测工具.
- 这种方法有助于控制的转化稳定的纳米材料的生产.
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