多触发超分子DNA/双二甲基乙烯水凝驱动光,氧化和化学刺激,用于形状记忆和自我愈合应用
Ziyuan Li1, Gilad Davidson-Rozenfeld2, Margarita Vázquez-González2
1Key Laboratory for Advanced Materials and Joint International Research Laboratory of Precision Chemistry and Molecular Engineering, Feringa Nobel Prize Scientist Joint Research Center, School of Chemistry and Molecular Engineering , East China University of Science & Technology , 130 Meilong Road , Shanghai , 200237 , China.
Journal of the American Chemical Society
|November 20, 2018
概括
新的基于碳甲基纤维素 (CMC) 的水凝使用光和氧化还原剂来控制度. 这些多触发材料具有高度应用的形状记忆和自我修复特性.
科学领域:
- 材料科学
- 聚合物化学
- 超分子化学
背景情况:
- 刺激响应的水凝为先进的应用提供可调节的特性.
- 滴乙烯 (DTE) 的光异构使光触发分子切换成为可能.
- 超分子相互作用,如捐赠者-接受者和G-四重复,可以形成可逆的水凝网络.
研究的目的:
- 开发基于甲基纤维素 (CMC) 的多触发,刺激反应的水凝.
- 设计具有可切换硬度,形状记忆和自我修复能力的水凝.
- 探索使用二乙烯 (DTE) 光异构和G-四重复合物作为触发剂.
主要方法:
- 合成含有多巴胺和核酸的CMC基水凝.
- 在光异构化引起的刚性变化中添加滴乙烯 (DTE).
- 使用K+稳定的G四重复和皇冠以太进行可逆交联.
主要成果:
- 通过光,氧化还原剂或K+/皇冠乙烯可切换刚性的双重和多重触发水凝.
- 在高度和低度状态之间证明可逆转变.
- 呈现出形状记忆和自我愈合特性在混合供体-接受体/G-四重体交联水凝中.
结论:
- 基于CMC的多触发型水凝可以精确控制材料的性能.
- 混合交叉连接策略可以实现形状记忆和自我修复等高级功能.
- 这些材料有望用于需要可调和响应的软材料的应用.
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