金属循环染色的超分子聚合物:通过替代物的变化进行光调节
Luonan Xu1, Xi Shen1, Zhixuan Zhou2
1College of Material, Chemistry and Chemical Engineering , Hangzhou Normal University , Hangzhou 310036 , P. R. China.
Journal of the American Chemical Society
|November 23, 2018
概括
研究人员使用金属配体协调和宿主-客体化学开发了光超分子聚合物. 这些可调节的聚合物具有创造先进发光材料和设备的潜力.
科学领域:
- 超分子化学
- 材料科学
- 光物理学
背景情况:
- 超分子聚合物通过非共价相互作用提供可调性特性.
- 金属-连接体协调和宿主-客体化学是构建复杂架构的强大工具.
- 开发具有可控排放和高效率的光材料对于光电子技术至关重要.
研究的目的:
- 开发一种可调节光的超分子聚合物制备方法.
- 探索金属 - 连接物协调和宿主 - 客体相互作用的组合,用于聚合物构造.
- 研究这些新材料的光物理特性和潜在应用.
主要方法:
- 协同驱动的白金 (II) 金属循环与二氧化捐赠者的自组装.
- 纳入21-皇冠-7 (P21C7) 主机-客户识别模式.
- 通过金属循环和二盐之间的宿主-客体相互作用形成超分子聚合物.
- 光物理性质的表征,包括辐射波长和量子产量.
主要成果:
- 合成了可见光谱 (427-593 nm) 的形金属环.
- 与单个金属循环相比,超分子聚合物表现出可调节的光和提高的效率.
- 一个发出白光的LED是使用具有高量子输出率 (0.22) 的发出黄色的超分子聚合物薄膜制造的.
结论:
- 为调整光超分子聚合物特性建立了一种多功能方法.
- 具有金属循环核心的高分子聚合物作为发光材料的有希望的平台.
- 开发的材料具有良好的可加工性和可调性,适用于光电子应用.
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