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相关概念视频

Electric Field01:16

Electric Field

12.8K
Consider two point charges, each exerting Coulomb force on the other. It is possible to describe the Coulomb interaction via an intermediate step by defining a new physical quantity called the electric field.
In the new picture, imagine that the first charge sets up an electric field independent of all other charges in the universe. When another charge comes in its vicinity, the second charge experiences an electric force depending on the electric field at that point. The source charge does not...
12.8K
Finding Electric Potential From Electric Field01:13

Finding Electric Potential From Electric Field

5.6K
For a system of charges, it is easy to calculate the system's potential because potential is a scalar quantity. However, in some instances where calculating the electric field is more straightforward than finding the potential, the electric field is used to calculate the system's potential. For a positive charge, the electric field is radially outward, and the potential is positive at any finite distance from the positive charge. In such an electric field, the motion away from the...
5.6K
Determining Electric Field From Electric Potential01:12

Determining Electric Field From Electric Potential

5.0K
The electric field and electric potential are related to each other. If the electric field at various points in the region of interest is known, it can be used to calculate the electric potential difference between any two points. Similarly, if the electric potential is known for various points, then it is possible to calculate the electric field.
In general, regardless of whether the electric field is uniform, it points in the direction of decreasing potential because the force on a positive...
5.0K
Electric Field Inside a Conductor01:20

Electric Field Inside a Conductor

7.4K
When a conductor is placed in an external electric field, the free charges in the conductor redistribute and very quickly reach electrostatic equilibrium. The resulting charge distribution and its electric field have many interesting properties, which can be investigated with the help of Gauss's law.
Suppose a piece of metal is placed near a positive charge. The free electrons in the metal are attracted to the external positive charge and migrate freely toward that region. This region then...
7.4K
Electric Field Lines01:25

Electric Field Lines

9.6K
The three-dimensional representation of the electric field of a positive point charge requires tracing the electric field vectors, whose lengths decrease as the square of their distance from the charge and which point away from the charge at each point. This vector field is no doubt challenging to visualize. The visualization of electric fields becomes quickly intractable as the number of charges increases.
The solution to this problem is to use electric field lines, which are not vectors but...
9.6K
Induced Electric Fields01:23

Induced Electric Fields

4.6K
The fact that emfs are induced in circuits implies that work is being done on the conduction electrons in the wires. What can possibly be the source of this work? We know that it’s neither a battery nor a magnetic field, as a battery does not have to be present in a circuit where current is induced, and magnetic fields never do any work on moving charges. The source of the work is in fact an electric field that is induced in the wires. For example, if a stationary conductor is placed in a...
4.6K

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Changing the Direction and Orientation of Electric Field During Electric Pulses Application Improves Plasmid Gene Transfer in vitro
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Changing the Direction and Orientation of Electric Field During Electric Pulses Application Improves Plasmid Gene Transfer in vitro

Published on: September 12, 2011

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内向电场作为选择性修改光化学反应的策略

Nicholas S Hill1, Michelle L Coote1

  • 1ARC Centre of Excellence for Electromaterials Science, Research School of Chemistry , Australian National University , Canberra , Australian Capital Territory 2601 , Australia.

Journal of the American Chemical Society
|November 24, 2018
PubMed
概括

研究人员使用时间依赖密度函数理论来研究充电函数组如何影响乙烯衍生物

科学领域:

  • 计算化学
  • 摄影化学
  • 有机化学

背景情况:

  • 在光化学中广泛研究了乙衍生物.
  • 控制激发状态属性对于开发新的光化学过程至关重要.
  • 内部电场为调整分子行为提供了潜在的方法.

研究的目的:

  • 探索充电函数组作为乙烯衍生物的内部电场的使用.
  • 研究这些内部电场如何影响光化学行为.
  • 确定这些静电效应的调节性和控制性.

主要方法:

  • 使用了时间依赖密度函数理论 (TD-DFT) 的计算.
  • 对具有充电功能组的各种乙烯衍生物进行了模拟.
  • 进行了替代物位置 (正体,元体,副体) 和电荷 (正体,负体) 的系统变化.

主要成果:

  • 不结合的带电组显著改变了高达-1.44 eV的激发状态稳定性.
  • 一个被替代的负电荷破坏了nπ*的稳定,并稳定了ππ*的转换.
  • 一个被替代的正电荷可以逆转这些效应; 位置变化调整了影响.

结论:

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  • 充电功能组可以作为可调整的内部电场来控制光化学行为.
  • 这些效应可以通过响应pH的酸和来开启/关闭.
  • 这种方法为提高光化学过程效率提供了一个有前途的策略.