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具有 λ 4 坐标 Si II 原子的几何强迫烯

Arseni Kostenko1, Matthias Driess1

  • 1Metalorganics and Inorganic Materials, Department of Chemistry , Technische Universität Berlin , Straße des 17. Juni 135, Sekr. C2 , 10623 Berlin , Germany.

Journal of the American Chemical Society
|December 1, 2018
PubMed
概括

研究人员合成了一种具有创纪录的SiSi键长度的高协调性disiene. 这种分子表现出动态的SiSi键行为和两价反应性,同时充当dysilene和bisilene.

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