固体与的反应性:介质和分子分解之间的竞争
Jiliang Zhang1, George F S Whitehead1, Troy D Manning1
1Materials Innovation Factory, Department of Chemistry , University of Liverpool , 51 Oxford Street , Liverpool L7 3NY , U.K.
Journal of the American Chemical Society
|December 1, 2018
概括
我们合成了K2Rubrene, 发现无形和晶体相. 金属多芳香碳化合物系统中的这种复杂性可能会影响超导性要求.
科学领域:
- 固态化学
- 材料科学
- 有机电子产品
背景情况:
- 金属间接的多芳香碳化合物 (PAH) 进行超导性研究.
- 一个很大的有机分子,
研究的目的:
- 合成和表征间流 (K2Rubrene).
- 了解与之间的固态反应路径.
- 研究由此产生的K-烯相的结构和化学特性.
主要方法:
- 使用K和KH来源合成K-烯化合物.
- 高分辨率粉末X射线衍射用于晶体结构的确定.
- 溶液核磁共振 (NMR) 光谱用于分析分解产物.
主要成果:
- K2Rubrene是主要阶段,通常是无形分解的副产品.
- 确定了三种K间隔化合物:K2Rubrene,K(RR*) 和KxR'.
- 在K2Rubrene的晶体结构中,K+被纳入了与rubrene强烈相互作用的大空隙.
结论:
- 合成K-烯显示出一个复杂的反应场景,涉及合和分解.
- 在K2Rubrene中,其结构结构与其他PAH有显著差异.
- 获得与超导性相关的减少PAH的无溶剂金属盐是复杂的.
相关概念视频
Molecular and Ionic Solids
20.1K
Crystalline solids are divided into four types: molecular, ionic, metallic, and covalent network based on the type of constituent units and their interparticle interactions.
Molecular Solids
Molecular crystalline solids, such as ice, sucrose (table sugar), and iodine, are solids that are composed of neutral molecules as their constituent units. These molecules are held together by weak intermolecular forces such as London dispersion forces, dipole-dipole interactions, or hydrogen bonds, which...
Molecular Solids
Molecular crystalline solids, such as ice, sucrose (table sugar), and iodine, are solids that are composed of neutral molecules as their constituent units. These molecules are held together by weak intermolecular forces such as London dispersion forces, dipole-dipole interactions, or hydrogen bonds, which...
20.1K
Molecular Comparison of Gases, Liquids, and Solids
55.1K
Particles in a solid are tightly packed together (fixed shape) and often arranged in a regular pattern; in a liquid, they are close together with no regular arrangement (no fixed shape); in a gas, they are far apart with no regular arrangement (no fixed shape). Particles in a solid vibrate about fixed positions (cannot flow) and do not generally move in relation to one another; in a liquid, they move past each other (can flow) but remain in essentially constant contact; in a gas, they move...
55.1K
Synthesis and Decomposition Reactions
38.2K
Synthesis and decomposition are two types of redox reactions. Synthesis means to make something, whereas decomposition means to break something. The reactions are accompanied by chemical and energy changes.
38.2K
Competition
24.8K
When organisms require the same limited resources within an environment, they may have to compete for them. Competition is a net-negative interaction. Even if two competing individuals or populations do not interact directly, the overall fitness of both competitors is lowered as a result of not having full access to the limited resource.
24.8K
Metallic Solids
20.6K
Metallic solids such as crystals of copper, aluminum, and iron are formed by metal atoms. The structure of metallic crystals is often described as a uniform distribution of atomic nuclei within a “sea” of delocalized electrons. The atoms within such a metallic solid are held together by a unique force known as metallic bonding that gives rise to many useful and varied bulk properties.
All metallic solids exhibit high thermal and electrical conductivity, metallic luster, and malleability....
All metallic solids exhibit high thermal and electrical conductivity, metallic luster, and malleability....
20.6K
Structures of Solids
17.7K
Solids in which the atoms, ions, or molecules are arranged in a definite repeating pattern are known as crystalline solids. Metals and ionic compounds typically form ordered, crystalline solids. A crystalline solid has a precise melting temperature because each atom or molecule of the same type is held in place with the same forces or energy. Amorphous solids or non-crystalline solids (or, sometimes, glasses) which lack an ordered internal structure and are randomly arranged. Substances that...
17.7K


