Na3MnZr(PO4)3:用于电池的高压阴极
Hongcai Gao1, Ieuan D Seymour2, Sen Xin1
1Texas Materials Institute, The University of Texas at Austin , Austin , Texas 78712 , United States.
Journal of the American Chemical Society
|December 4, 2018
概括
电池提供了有前途的大规模储能. 作为阴极材料,NASICON结构的Na3MnZr(PO4) 3具有卓越的性能,可实现高容量和优异的离子能量存储周期.
科学领域:
- 材料科学
- 电化学
- 能量储存
背景情况:
- 电池是大规模储能的关键.
- 开发高性能阴极材料至关重要.
- 酸阴极正在调查中.
研究的目的:
- 将NASICON结构的Na3MnZr ((PO4) 3) 作为一种新型阴极材料进行报告.
- 为了评估电池的电化学性能.
- 了解它的结构和电化学特性.
主要方法:
- 电化学测试 (充/放电周期)
- 结构分析
- 密度函数理论 (DFT) 的计算.
主要成果:
- 与其他酸盐相比,Na3MnZr(PO4) 3具有更高的性能.
- 实现了105mAh的高放电容量.
- 在500个循环后保持91%的容量.
- 在4.0和3.5V的电压下可逆访问Mn4+/Mn3+和Mn3+/Mn2+氧化还原电偶.
- 在化/脱过程中的小体积变化.
- 抑制了Mn3+的雅恩-泰勒扭曲.
结论:
- Na3MnZr ((PO4) 3) 是电池的一个非常有前途的阴极.
- 它的结构促进了高能量密度和长周期寿命.
- 该材料为离子的插入/提取提供了稳定的电化学途径.
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