在水中自组装材料的两共聚物的自分类:聚合物可以自我识别
Shota Imai1, Mikihito Takenaka2,3, Mitsuo Sawamoto1,4
1Department of Polymer Chemistry, Graduate School of Engineering , Kyoto University , Katsura, Nishikyo-ku, Kyoto 615-8510 , Japan.
Journal of the American Chemical Society
|December 4, 2018
概括
与聚乙烯糖醇 (PEG) 和疏水性链的两性共聚物表现出动态的自我分类,形成明显的. 这种自我识别行为使得具有选择性粘附的水凝能够自我愈合.
科学领域:
- 聚合物化学
- 材料科学
- 超分子化学
背景情况:
- 两性聚合物在溶液中自组成各种纳米结构.
- 在竞争条件下控制自组装仍然是一个挑战.
- 动态自我排序为精确的纳米结构形成提供了一个新的机制.
研究的目的:
- 研究两性随机共聚物的动态自我排序行为.
- 探索共聚合物组成和悬挂组对自我分类的影响.
- 通过这种现象开发自愈水凝等先进材料.
主要方法:
- 用聚乙烯糖醇 (PEG) 和疏水性基悬挂合成两性随机共聚物.
- 动态光散射 (DLS) 和传输电子显微镜 (TEM) 用于细胞的表征.
- 评估水凝性能的风湿学研究.
主要成果:
- 聚合物在水性介质,水凝和表面上表现出普遍的动态自我分类.
- 自排序取决于共聚合物组成和基,形成离散的,大小受控的粒.
- 完全相同的聚合物链,即使存在不同的对应物.
- ABA-triblock共聚物表现出自我愈合和选择性粘合的水凝特性.
结论:
- 动态自我排序是两性共聚物的内在性质,由它们的主要结构决定.
- 这种行为可以创建具有可控属性的定义良好的纳米结构.
- 开发的材料显示出需要自我修复和选择性粘附的应用的潜力.
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