具有可修改孔的高排序的纳米孔状二维共价有机框架及其在水净化和离子选中的应用
Valerie A Kuehl, Jiashi Yin, Phuoc H H Duong
1Central Instrument Facility , Colorado State University , Fort Collins , Colorado 80523 , United States.
Journal of the American Chemical Society
|December 5, 2018
概括
研究人员开发了新的纳米多孔聚合物膜. 这些共价有机框架 (COF) 对大小和电荷具有很高的选择性,改善了能源和水净化技术.
科学领域:
- 材料科学
- 纳米技术
- 化学工程
背景情况:
- 膜技术对于能源供应和清洁水的生产至关重要.
- 基于尺寸和电荷的高选择性是有效分离过程的关键.
- 开发用于膜的先进材料仍然是一个重大挑战.
研究的目的:
- 开发一种灵活的合成协议,用于制造高度有序的二维纳米多聚物材料.
- 为了使这些材料具有功能,称为共价有机框架 (COF),具有特定的化学性质.
- 制造和测试这些新型COF用于分离应用的膜.
主要方法:
- 使用灵活的合成协议创建二维纳米多孔材料 (COF).
- 功能组,特别是基组,被纳米孔内纳入.
- 为了性能评估,使用这些碳氧化COF制造了膜.
主要成果:
- 合成的COF形成了高度有序的二维纳米孔状结构.
- 由这些碳化COF制成的膜具有很高的水透性.
- 这些膜在充电量和尺寸上都表现出显著的选择性.
结论:
- 已经建立了一种用于合成功能化COF的多功能方法.
- 碳氧化COF膜显示出高效分离技术的前景.
- 这些先进的膜可以显著影响能源和水净化.
更多相关视频
11:55Membrane Transport Processes Analyzed by a Highly Parallel Nanopore Chip System at Single Protein Resolution
Published on: August 16, 2016
12.1K
08:42Microfluidic-based Synthesis of Covalent Organic Frameworks COFs: A Tool for Continuous Production of COF Fibers and Direct Printing on a Surface
Published on: July 10, 2017
14.1K
相关概念视频
Pore Transport and Ion-Pair Transport
1.3K
Pore transport and ion-pair formation are critical mechanisms for the absorption and distribution of drugs in the body.
Pore transport, also known as convective transport, is a process where small molecules like urea, water, and sugars rapidly cross cell membranes as though there were channels or pores in the membrane. Although direct microscopic evidence is limited but the concept of pores or channels is widely accepted based on physiological evidence. Despite the lack of direct...
Pore transport, also known as convective transport, is a process where small molecules like urea, water, and sugars rapidly cross cell membranes as though there were channels or pores in the membrane. Although direct microscopic evidence is limited but the concept of pores or channels is widely accepted based on physiological evidence. Despite the lack of direct...
1.3K
Network Covalent Solids
16.2K
Network covalent solids contain a three-dimensional network of covalently bonded atoms as found in the crystal structures of nonmetals like diamond, graphite, silicon, and some covalent compounds, such as silicon dioxide (sand) and silicon carbide (carborundum, the abrasive on sandpaper). Many minerals have networks of covalent bonds.
To break or to melt a covalent network solid, covalent bonds must be broken. Because covalent bonds are relatively strong, covalent network solids are typically...
To break or to melt a covalent network solid, covalent bonds must be broken. Because covalent bonds are relatively strong, covalent network solids are typically...
16.2K
Covalent Bonds
162.2K
Overview
162.2K
Covalent Bonds
10.9K
Overview
When two atoms share electrons to complete their valence shells, they create a covalent bond. An atom's electronegativity—the force with which shared electrons are pulled towards an atom—determines how the electrons are shared. Molecules formed with covalent bonds can be either polar or nonpolar. Atoms with similar electronegativities form nonpolar covalent bonds; the electrons are shared equally. Atoms with different electronegativities share electrons unequally,...
When two atoms share electrons to complete their valence shells, they create a covalent bond. An atom's electronegativity—the force with which shared electrons are pulled towards an atom—determines how the electrons are shared. Molecules formed with covalent bonds can be either polar or nonpolar. Atoms with similar electronegativities form nonpolar covalent bonds; the electrons are shared equally. Atoms with different electronegativities share electrons unequally,...
10.9K
Covalent Bonding and Lewis Structures
61.3K
Compared to ionic bonds, which results from the transfer of electrons between metallic and nonmetallic atoms, covalent bonds result from the mutual attraction of atoms for a “shared” pair of electrons.
61.3K
Covalently Linked Protein Regulators
9.6K
Proteins can undergo many types of post-translational modifications, often in response to changes in their environment. These modifications play an important role in the function and stability of these proteins. Covalently linked molecules include functional groups, such as methyl, acetyl, and phosphate groups, and also small proteins, such as ubiquitin. There are around 200 different types of covalent regulators that have been identified.
These groups modify specific amino acids in a protein....
These groups modify specific amino acids in a protein....
9.6K
