基于的两协调乳化剂的合理设计
Subhadeep Saha1, Björn Holzapfel1, Yen-Ting Chen2
1Faculty of Chemistry and Chemical Biology , TU Dortmund University , Otto-Hahn-Str. 6 , 44227 Dortmund , Germany.
Journal of the American Chemical Society
|December 6, 2018
概括
研究人员创造了新的基于子的双胞胎双胞胎 (CGAs),它们可以自组装成囊泡. 这些结构可以形成链条并稳定油中的乳液,扩大孔隙协调的应用.
科学领域:
- 超分子化学
- 材料科学
- 纳米技术
背景情况:
- 有孔的协调可以控制客人吸收,药物输送,分离和催化.
- 对于自组装材料的3D形状和外部功能化存在有限的研究.
研究的目的:
- 从功能化协调中开发新的自组装材料.
- 研究双子座两动物的自我组装行为和特性.
主要方法:
- 合成基于阿克里的 (L^A) 和衍生于的 (L^B) 配体.
- 连接物自组装成异构协调 cis-[Pd2(L^A) 2 ((L^B) 2+ (CGA-1).
- 使用冷TEM和液体细胞传导电子显微镜 (LC-TEM) 的表征.
主要成果:
- 在极性溶剂中,带有异构侧链的阴离子 (CGA-1) 自组成囊泡 (直径≥100 nm).
- 通过长距离的相互作用, 形成链条和项链.
- 这些子表现出稳定油中的乳液的能力.
结论:
- 基于的双胞胎双胞胎 (CGAs) 可以形成自组装的囊泡结构.
- 这些CGA具有独特的聚合行为和乳液稳定能力.
- 这些发现扩大了协调在材料科学和纳米技术中的实用性.
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