超微型丰富的金属基聚物作为氧气演变的催化剂
Xin-Bao Han1, Xing-Yan Tang1, Yue Lin
1State Key Laboratory for Physical Chemistry of Solid Surfaces, and Department of Chemistry, College of Chemistry and Chemical Engineering , Xiamen University , Xiamen , 361005 , China.
Journal of the American Chemical Society
|December 13, 2018
概括
研究人员开发了一种新的分子到集群方法,以创建超小的,具有成本效益的三金属催化剂,以在水电解中有效地进化氧气,从而推进可再生能源解决方案.
科学领域:
- 催化剂
- 材料科学
- 电化学
背景情况:
- 贵金属催化剂对氧化演化反应 (OER) 有效,但价格昂贵且稀缺.
- 水的电解是清洁和可再生能源生产的关键.
- 开发具有成本效益和高活性的开放式资源催化剂至关重要.
研究的目的:
- 报告一种用于合成超小三金属集群的新型分子到集群策略.
- 研究这些聚合物的催化性能,用于氧的演化反应.
- 展示一个新途径来创建精确定义的亚纳米过渡金属集群.
主要方法:
- 使用聚氧金属分子作为前体.
- 采用分子到的策略来合成三金属.
- 结果的超细 (0.8 nm) 过渡金属集群具有可控制的组成.
主要成果:
- 获得了具有控制化学组成的超小 (0.8 nm) 过渡金属集群.
- 在性介质中表现出高效的氧化演化反应 (OER).
- 催化剂在10 mA cm-2时表现出192 mV的超电位,36 mV dec-1的塔菲尔斜率,以及30 h的稳定性.
结论:
- 通过分子到集群的策略,成功地产生了高效和稳定的开放式反应催化剂.
- 开发的三金属集群为贵金属提供了经济有效的替代品.
- 这种合成方法在OER催化之外也有潜在的应用.
相关概念视频
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