研究电子在稳定具有电催化作用的低电压COI中间体中的作用
David P Hickey1, Christopher Sandford1, Zayn Rhodes1
1Department of Chemistry , University of Utah , 315 South 1400 East , Salt Lake City , Utah 84112 , United States.
Journal of the American Chemical Society
|January 2, 2019
概括
研究人员探索了新的复合物用于电催化. 双酸稳定反应性 (I) 种,使新型催化反应成为可能,并促进有机金属化学.
科学领域:
- 有机金属化学
- 电催化
背景情况:
- 复合物是一个有前途的电催化剂.
- 稳定活性的状态至关重要,但由于不成比例而具有挑战性.
- 通常使用多牙,重的连接体.
研究的目的:
- 作为短暂I物种的替代稳定策略,研究双电子不对称的配体.
- 了解复合不成比例的基本机制.
- 确定用于电催化的新型复合物.
主要方法:
- 电化学产生 (I) 复合物.
- 测量不成比例率以评估稳定性
- 系统变异的N,N-bidentate连接体.
主要成果:
- Co ((I) Cl复合体的稳定性与热力学特性相关,表明外层电子转移.
- Co ((I) Br复合物被电子不对称的配体优先稳定,这表明不同的不成比例机制.
- 确定了具有增强稳定性的特定复合物.
结论:
- 双酸电子不对称配体为稳定反应性中介提供了有效的替代品.
- 发现了Co (I) Cl和Co (I) Br复合物的不同不成比例机制.
- 为设计新的基电催化剂提供了基础.
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