可切换的Schottky接口:同时增强输出电流和减少泄漏电流
Guirong Su1, Sha Yang1, Shuang Li1
1Nano and Heterogeneous Materials Center, School of Materials Science and Engineering , Nanjing University of Science and Technology , Nanjing 210094 , Jiangsu , China.
Journal of the American Chemical Society
|January 5, 2019
概括
通过控制分子吸附状态,研究人员开发了有机Schottky二极管,具有改进的反向偏差特征. 这克服了基于的二极管的局限性,实现了低泄漏电流和高输出.
科学领域:
- 材料科学
- 凝聚物质物理学
- 纳米科学
背景情况:
- 金属半导体接触对纳米电子非常重要,Schottky二极管提供快速切换但高反向泄漏.
- 传统的基于的Schottky二极管在改善反向偏差特征而不会影响前向性能方面面临物理限制.
研究的目的:
- 调查有机基二极管在克服传统肖特基二极管的局限性的潜力.
- 使用可逆分子吸附状态来提高二极管性能的新方法.
主要方法:
- 密度函数理论 (DFT) 模拟用于模拟分子吸附和肖特基屏障高度.
- 不平衡格林函数 (NEGF) 运输计算以验证纠正行为.
主要成果:
- 对于Cu的不同吸附状态,已经证明了不同的Scottky屏障高度.
- 化学吸收状态产生了更高的肖特基屏障,显著降低了反向泄漏电流.
- 一个被物理吸收的状态导致了较低的肖特基屏障,使得前向偏差下的输出电流更大.
结论:
- 分子吸附状态之间的可逆过渡为设计具有优异反向偏差特性的有机肖特基二极管提供了可行的策略.
- 这种方法可以同时改善低泄漏电流和高输出电流,解决纳米电子设备设计的关键挑战.
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