在基质金属有机组件网络中以键辅助打破对称性
Felix J Rizzuto1, Patrick Pröhm1, Alex J Plajer1
1Department of Chemistry , University of Cambridge , Lensfield Road , Cambridge CB2 1EW , U.K.
Journal of the American Chemical Society
|January 8, 2019
概括
基质连接物自组合成多种金属有机结构,其结构由成分比率,溶剂和化单位决定. 精确的组装控制允许选择性地放置阿奇拉和奇拉单元,从而产生复杂的低对称结构.
科学领域:
- 超分子化学
- 材料科学
- 晶体学
背景情况:
- 金属有机框架 (MOF) 是具有调节性质的多功能材料.
- 控制性联体的自我组装对于创建复杂的架构至关重要.
- 了解影响自组合的因素,如性,溶剂和键,是关键.
研究的目的:
- 阐明金属有机架构自组合中的性,酸盐,溶剂和结的相互作用.
- 通过使用纯和血配体,探索多样化的三维金属有机结构的形成.
- 为了研究在体系统中选择性地放置体单位.
主要方法:
- 通过使用纯和血配体,合成新型的三维金属有机结构.
- 连接物比率,溶剂 (MeCN,MeOH) 和化单位 (双,三) 的系统变化.
- 纳入阿基拉联体构建块和对二重选择性产品生成的分析.
主要成果:
- 乙烯酸纯联体形成了M4L4组件,而血混合物产生了M3L3堆.
- 在M3L3等离子体中观察到二分之一的R和S等离子体.
- 选择性生产的新型M2L2和M3L2组件.
- 选择性地将Achiral单元放置在基于奇拉环境的三层异构架构或中心结构中.
- 在单个配体内结合R和S立体中心导致二分立体选择性产物生成.
结论:
- 几何互补性和键显著影响金属有机结构的自组装.
- 对组装条件的精确控制可以选择性地形成低对称的复杂结构.
- 这项工作为设计和合成具有定制性质的新奇金属有机材料提供了框架.
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