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Hydrogen Bonds00:26

Hydrogen Bonds

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Hydrogen bonds are weak attractions between atoms that have formed other chemical bonds. One of these atoms is electronegative, like oxygen, and has a partial negative charge. The other is a hydrogen atom that has bonded with another electronegative atom and has a partial positive charge.
Hydrogen Bonds Control the World!
Because hydrogen has very weak electronegativity when it binds with a strongly electronegative atom, such as oxygen or nitrogen, electrons in the bond are unequally shared....
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Hydrogen Bonds01:04

Hydrogen Bonds

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A hydrogen bond is formed when a weakly positive hydrogen atom already bonded to one electronegative atom (for example, the oxygen in the water molecule) is attracted to another electronegative atom from another polar molecule, such as water (H2O), hydrogen fluoride (HF), or ammonia (NH3). The huge electronegativity difference between the H atom (2.1) and the atom to which it is bonded (4.0 for an F atom, 3.5 for an O atom, or 3.0 for an N atom), combined with the very small size of an H atom...
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IR Spectrum Peak Broadening: Hydrogen Bonding01:23

IR Spectrum Peak Broadening: Hydrogen Bonding

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The vibrational frequency of a bond is directly proportional to its bond strength. As a result, stronger bonds vibrate at higher frequencies, while weaker bonds vibrate at lower frequencies. The stretching vibration of the strong O–H bond in alcohols and phenols (very dilute solution or gas phase) appears as a sharp peak at 3600–3650 cm−1.
However, the extent of hydrogen bonding influences the observed stretching frequency and band broadening. Intermolecular or intramolecular...
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Organic Compounds03:02

Organic Compounds

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All living things are formed mostly of carbon compounds called organic compounds. The category of organic compounds includes both natural and synthetic compounds that contain carbon. Although a single, precise definition has yet to be identified by the chemistry community, most agree that a defining trait of organic molecules is the presence of carbon as the principal element, bonded to hydrogen and other carbon atoms. However, some carbon-containing compounds such as carbonates, cyanides, and...
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Peptide Bonds02:43

Peptide Bonds

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A peptide bond covalently attaches amino acids through a dehydration reaction. One amino acid's carboxyl group and another amino acid's amino group combine, releasing a water molecule. The resulting bond is the peptide bond. The products that such linkages form are peptides. As more amino acids join this growing chain, the resulting chain is a polypeptide. Each polypeptide has a free amino group at one end. This end has the N-terminal, or the amino-terminal, and the other end has a free...
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Valence Bond Theory02:45

Valence Bond Theory

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Overview of Valence Bond Theory
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具有酸反应性结的有机框架

Ichiro Hisaki1, Yuto Suzuki2, Eduardo Gomez3

  • 1Research Institute for Electronic Science , Hokkaido University , Kitaku, Sapporo , Hokkaido 001-0020 , Japan.

Journal of the American Chemical Society
|January 8, 2019
PubMed
概括

一种新的有机框架 (HOF) 显示了可逆的酸诱导的颜色变化. 这一发现为开发智能,响应刺激的材料开辟了新的途径.

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科学领域:

  • 材料科学
  • 超分子化学
  • 有机化学

背景情况:

  • 有机基框架 (HOF) 是具有可调节性质的晶体材料.
  • 对于先进的传感和自适应技术来说,

研究的目的:

  • 构建和描述一种新型的响应酸的HOF.
  • 在酸暴露时调查HOF的光物理性质和结构行为.

主要方法:

  • 单晶X射线衍射用于结构确定.
  • 气体吸附实验用于孔隙性评估.
  • 用于光化学研究的五秒光谱和光显微镜.

主要成果:

  • 合成了一种具有高热稳定的多孔HOF (CPHATN-1a).
  • 观察到超快的分子内电荷转移和单位间质子转移反应.
  • 经过酸蒸气暴露,可以证明可逆的黄色至红棕色变化和排放调节.

结论:

  • 这项工作呈现了第一个呈现酸反应色彩变化的HOF.
  • 开发的HOF显示出在化学传感和智能材料中的应用潜力.
  • 这些发现有助于理解对刺激有反应的HOF.