光切换和光色结合之间的机械相互作用[Pd2二甲基乙烯4]协调
Ru-Jin Li1, Julian J Holstein1, Wolf G Hiller1
1Faculty of Chemistry and Chemical Biology , TU Dortmund University , Otto-Hahn-Straße 6 , 44227 Dortmund , Germany.
Journal of the American Chemical Society
|January 9, 2019
概括
使用dithienylethene (DTE) 配体的光色协调可以在光照射时释放客人. 这项研究揭示,仅关闭一个光开关就会驱逐奇拉客, 提供了对子机制的新见解.
科学领域:
- 超分子化学
- 摄影化学
- 材料科学
背景情况:
- 光色协调提供光控制的客体封装和释放.
- 之前的研究集中在完全切换状态上,不清楚中间的光异构化机制.
研究的目的:
- 在dithienylethene (DTE) 基协调中进行光异构化时,研究客体排放的机制细节.
- 了解光异构化步骤和腔内客体位置之间的相互作用.
主要方法:
- 基于DTE的新光色协调的合成与内在的性.
- 宿主-客人复合用合1R--或1S--硫酸盐 (CSA).
- 使用循环二极化 (CD),DOSY NMR,离子运动质谱学和X射线晶体学监测光异构化和奇拉性转移.
主要成果:
- 通过CD光谱观察从客体 (CSA) 转移到宿主.
- 辐射诱导了稳定的"封闭"光异构体,锁定了具有高反体过剩的性.
- 证据表明,关闭一个光开关足以将形客人赶出子.
结论:
- 这项研究为DTE中的光异构化中间步骤提供了前所未有的洞察力.
- 在第一个光开关关闭后,客人就会被驱逐出去,不需要完全的子转换.
- DTE配体的内在性作为监测光异构和客体动态的有效报告者.
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