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相关概念视频

Conservation of Protein Domains Over Different Proteins02:26

Conservation of Protein Domains Over Different Proteins

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Protein domains are small structurally independent units that are part of a single amino acid chain.  Although these domains are often structurally independent, they may rely on synergistic effects to perform their functions as part of a larger protein. Protein domains may be conserved within the same organism, as well as across different organisms.
A limited set of protein domains often duplicate and recombine during evolution. These domains can be organized in different combinations to...
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Stratified Sampling Method01:16

Stratified Sampling Method

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Sampling is a technique to select a portion (or subset) of the larger population and study that portion (the sample) to gain information about the population. The sampling method ensures that samples are drawn without bias and accurately represent the population. Because measuring the entire population in a study is not practical, researchers use samples to represent the population of interest.
To choose a stratified sample, divide the population into groups called strata and then take a...
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Organic Compounds03:02

Organic Compounds

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All living things are formed mostly of carbon compounds called organic compounds. The category of organic compounds includes both natural and synthetic compounds that contain carbon. Although a single, precise definition has yet to be identified by the chemistry community, most agree that a defining trait of organic molecules is the presence of carbon as the principal element, bonded to hydrogen and other carbon atoms. However, some carbon-containing compounds such as carbonates, cyanides, and...
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Bonding in Metals02:32

Bonding in Metals

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Metallic bonds are formed between two metal atoms. A simplified model to describe metallic bonding has been developed by Paul Drüde called the “Electron Sea Model”. 
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Metallic Solids02:37

Metallic Solids

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Metallic solids such as crystals of copper, aluminum, and iron are formed by metal atoms. The structure of metallic crystals is often described as a uniform distribution of atomic nuclei within a “sea” of delocalized electrons. The atoms within such a metallic solid are held together by a unique force known as metallic bonding that gives rise to many useful and varied bulk properties.
All metallic solids exhibit high thermal and electrical conductivity, metallic luster, and malleability....
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Alkali Metals03:06

Alkali Metals

24.6K
Group 1 elements are soft and shiny metallic solids. They are malleable, ductile, and good conductors of heat and electricity. The melting points of the alkali metals are unusually low for metals and decrease going down the group, while the density increases going down the group with the exception of potassium (Table 1).
Table 1: Properties of the alkali metals
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相关实验视频

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Synthesis of a Thiol Building Block for the Crystallization of a Semiconducting Gyroidal Metal-sulfur Framework
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多变量分层金属有机框架:使用域构建块进行多样化

Tian-Yi Luo, Chong Liu, Xing Yee Gan

    Journal of the American Chemical Society
    |January 15, 2019
    PubMed
    概括

    域构建块 (DBB) 能够实现多样化,复杂的金属有机框架 (MOF). 这种方法可以创建具有可调节性质的多变量MOF和分层MOF (sMOF),克服链接器交换等挑战.

    科学领域:

    • 材料科学
    • 化学学
    • 纳米技术

    背景情况:

    • 金属有机框架 (MOF) 提供可调节的孔隙性和功能性.
    • 目前的MOF合成通常会产生有限的结构多样性和复杂性.
    • 控制MOF中的组成异质性仍然是一个重大挑战.

    研究的目的:

    • 介绍MOF设计的域构建块 (DBB).
    • 制定创建多变量和分层MOF (sMOF) 的战略.
    • 调查链接器交换效应,并提出在小规模市场中减轻影响的策略.

    主要方法:

    • DBB方法的概念化和应用.
    • 用同心DBB合成UiO-67sMOF颗粒
    • 合成后修改和sMOF结构的特征.
    • 制备sMOF纳米颗粒复合材料.

    主要成果:

    • 证明一小组分子构建块可以通过DBB生成一个庞大的多变量MOF库.
    • 成功构建了多个同心DBB的UiO-67sMOF.
    • 识别了链接器交换对DBB完整性的不利影响,并提出了有效的缓解策略.

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  • 展示了选择性地处理和操纵sMOF中的单个层面的能力.
  • 制造的sMOF纳米颗粒复合材料,突出了合成方法的多功能性.
  • 结论:

    • DBB 方法是提高 MOF 多样性和复杂性的有效策略.
    • 可以精确设计UiO-67sMOF以控制的DBB序列和组合.
    • 单个层的合成后修改是可行的,使定制功能成为可能.
    • 开发的方法为创建先进的MOF材料和复合材料提供了多功能途径.