聚合物/复合物的多色机色化,具有双重明确的机器光
Takahiro Kosuge1,2, Xiaolei Zhu3, Vivian M Lau2,4
1Department of Chemical Science and Engineering , Tokyo Institute of Technology , 2-12-1 Ookayama , Meguro-ku, Tokyo 152-8550 , Japan.
Journal of the American Chemical Society
|January 25, 2019
概括
这项研究引入了一种新的多色机色聚合物/化合物. 由于两个嵌入的机械染色体,该材料在应对机械应力,溶剂和时间时呈现出明显的颜色变化 (蓝色,绿色,色).
科学领域:
- 材料科学
- 聚合物化学
- 纳米技术
背景情况:
- 机色材料在机械应力时会改变颜色.
- 开发具有可调节响应的多色机色材料是一项挑战.
- 聚合物/复合材料为先进材料设计提供了多功能平台.
研究的目的:
- 开发一种新的多色机色聚合物/化合物.
- 为了研究含有二甲基和纳夫托皮兰的复合物的机色特性.
- 了解材料结构,刺激和颜色反应之间的关系.
主要方法:
- 聚合物/复合物的制造具有不同的领域.
- 两种不同机色素的结合:二二和纳夫托皮兰.
- 使用固态紫外线吸收光谱,初始引导分子动力学模拟和能量通路的计算分析进行了表征.
主要成果:
- 这种复合材料具有多色机色,显示蓝色,绿色和色.
- 根据不同的机械刺激强度,溶剂添加和时间观察到颜色变化.
- 机色体的不同域位 (富含和富含聚合物) 影响了它们的特性和激活的颜色.
结论:
- 一种全新的多色机色聚合物/化合物成功开发.
- 观测到的机色体是由两个不同的机色体及其局部环境之间的相互作用引起的.
- 这种复合材料在需要视觉压力或环境传感的应用中具有潜力.
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