在金属有机框架中吸收冲击波能量
Xuan Zhou1, Yu-Run Miao1, William L Shaw1
1Department of Chemistry , University of Illinois at Urbana-Champaign , Urbana , Illinois 61801 , United States.
Journal of the American Chemical Society
|February 1, 2019
概括
焦化物 - 胺酸框架 (ZIF-8) 通过多种机制有效消散冲击波,包括压缩和键断裂. 这种多孔材料对先进的抗冲击装甲应用具有前景.
科学领域:
- 材料科学
- 机械学
- 化学学
背景情况:
- 金属有机框架 (MOF) 通过各种机制显示能量消耗的潜力.
- 静态高压研究表明MOF可以提供多功能冲击消散.
- 在动态冲击压缩下对MOF行为存在有限的数据.
研究的目的:
- 调查焦化物-胺酸框架 (ZIF-8) 的冲击波减弱能力.
- 了解多孔ZIF-8中冲击消散的机制.
- 与传统标准相比,评估ZIF-8作为一个吸震材料.
主要方法:
- 通过解,多孔ZIF-8测量冲击波减弱.
- 消散过程的分析,包括粉末紧缩,纳米孔崩和化学键断裂.
- 在不同冲击速度下对ZIF-8与PMMA的能量吸收进行比较分析.
主要成果:
- 通过多种过程消散冲击波:粉末紧缩,纳米孔崩和化学键断裂.
- 在ZIF-8中,冲击能量吸收与其厚度成正比.
- 与PMMA相比,ZIF-8具有更高的冲击能量吸收能力,在0.75公里/秒时吸收的能量是每单位质量的7倍,在1.6公里/秒时吸收的能量是2.5倍.
结论:
- ZIF-8具有多功能冲击波消散能力.
- 可以设计ZIF-8层的厚度以达到所需的减震水平.
- 像ZIF-8这样的工程MOF为增强的抗冲击材料提供了保护.
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