原子分散的铁氧化物定在Pt上,用于在H2中优先氧化CO
Lina Cao1,2, Wei Liu3, Qiquan Luo1,2
1Hefei National Laboratory for Physical Sciences at the Microscale, University of Science and Technology of China, Hefei, China.
Nature
|February 1, 2019
概括
在纳米颗粒上原子分散的铁氧化物为从燃料中去除一氧化碳 (CO) 杂质提供了一个新的解决方案. 这种突破性的催化剂在广泛的温度范围内有效运作, 提高了质子交换膜燃料电池的性能.
科学领域:
- 催化剂
- 材料科学
- 电化学
背景情况:
- 质子交换膜燃料电池 (PEMFC) 对清洁能源应用具有前景.
- 燃料中一氧化碳 (CO) 的催化剂中毒阻碍了PEMFC的效率.
- 通过优先氧化碳 (PROX) 净化机载是一种关键的挑战.
研究的目的:
- 开发一种高活性和选择性催化剂以去除中的二氧化碳.
- 为了使PEMFC运行在广泛的温度范围内实现高效的CO氧化.
- 解决燃料电池技术中的催化剂中毒问题.
主要方法:
- 在 (Pt) 纳米颗粒上选择性沉积原子分散的氧化铁.
- 在现场测量X射线吸收细结构 (XAFS).
- 密度函数理论 (DFT) 的计算.
主要成果:
- 在1983K温度范围内通过PROX实现了完全和100%的选择性CO去除.
- 比传统的Pt/氧化铁催化剂高出30倍的质量特异活性.
- 确定Fe1 ((OH) x集群在Pt纳米粒子上作为活跃的界面部位.
结论:
- 在Pt纳米颗粒上原子分散的铁氧化物代表了一类新型的高活性催化剂.
- 孤立的过渡金属复合物为催化剂设计提供了创新策略.
- 这种方法提高了CO净化,提高了PEMFC的性能和耐用性.
相关概念视频
Oxidation Numbers
42.5K
In redox reactions, the transfer of electrons occurs between reacting species. Electron transfer is described by a hypothetical number called the oxidation number (or oxidation state). It represents the effective charge of an atom or element, which is assigned using a set of rules.
42.5K
The Anchoring-and-Adjustment Heuristic
7.8K
In order to make good decisions, we use our knowledge and our reasoning. Often, this knowledge and reasoning is sound and solid. However, sometimes, we are swayed by biases or by others manipulating a situation. For example, let’s say you and three friends wanted to rent a house and had a combined target budget of $1,600. The realtor shows you only very run-down houses for $1,600 and then shows you a very nice house for $2,000. Might you ask each person to pay more in rent to get the...
7.8K
Oxidation-Reduction Reactions
75.6K
Oxidation–Reduction Reactions
75.6K
Pyruvate Oxidation
168.8K
After glycolysis, the charged pyruvate molecules enter the mitochondria via active transport and undergo three enzymatic reactions. These reactions ensure that pyruvate can enter the next metabolic pathway so that energy stored in the pyruvate molecules can be harnessed by the cells.
First, the enzyme pyruvate dehydrogenase removes the carboxyl group from pyruvate and releases it as carbon dioxide. The stripped molecule is then oxidized and releases electrons, which are then picked up by NAD+...
First, the enzyme pyruvate dehydrogenase removes the carboxyl group from pyruvate and releases it as carbon dioxide. The stripped molecule is then oxidized and releases electrons, which are then picked up by NAD+...
168.8K
Anchoring Junctions
5.0K
Anchoring junctions are multiprotein complexes that help cells connect to other cells and the extracellular matrix. Anchoring junctions are present on the lateral and basal surfaces of cells, providing strong and flexible connections. Focal adhesions are often formed due to cell interactions with the ECM substrata, which initiate signal transduction via kinase cascades and other mechanisms. Together, they provide stability and tissue integrity. There are three types of anchoring junctions:...
5.0K
Lipids as Anchors
7.3K
In the plasma membrane, the lipids forming the bilayer can also act as an anchor to tether proteins to the membrane. The three main types of lipid anchors found in eukaryotes are – prenyl groups, fatty acyl groups, and glycosylphosphatidylinositol or GPI groups. Prenyl and fatty acyl groups act as anchors on the cytosolic surface of the membrane, whereas GPI anchors proteins on the extracellular side.
The carboxy-terminal of most of the prenylated proteins, such as Ras proteins, contains...
The carboxy-terminal of most of the prenylated proteins, such as Ras proteins, contains...
7.3K


