铁硫聚合物的氧活性1D协调聚合物
Noah E Horwitz1, Jiaze Xie1, Alexander S Filatov1
1Department of Chemistry , University of Chicago , Chicago , Illinois 60637 , United States.
Journal of the American Chemical Society
|February 5, 2019
概括
研究人员使用铁硫 (Fe4S4) 聚合物和有机链接剂制造了新的协调聚合物. 这些材料在聚合物化学减少时显著增加电导率.
科学领域:
- 材料科学
- 无机化学
- 纳米技术
背景情况:
- 铁硫 (Fe4S4) 集群是原型的氧化还原活性无机构建块.
- 协调聚合物提供可调节的结构和性能,用于先进的应用.
研究的目的:
- 合成和描述包含无限链Fe4S4集群的新型协调聚合物.
- 研究这些基于Fe4S4的材料的电子和导电特性.
主要方法:
- 用同步射线粉碎衍射测定晶体结构.
- 紫外线可见和莫斯尔光谱用于电子属性分析.
- 化学减少引入电荷载体并评估导电性.
主要成果:
- 有无限Fe4S4集群链的协调聚合物的成功合成.
- 在溶液中显示可溶性和结构完整性.
- 在减少Fe4S4集群时,电导率增加了四个数量级.
结论:
- 4S4集群作为设计新型协调聚合物的多功能氧化还原活性构件.
- 这些材料具有可调节的电子特性和增强的导电性,这表明电子应用的潜力.
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