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Protons and neutrons, collectively called nucleons, are packed together tightly in a nucleus. With a radius of about 10−15 meters, a nucleus is quite small compared to the radius of the entire atom, which is about 10−10 meters. Nuclei are extremely dense compared to bulk matter, averaging 1.8 × 1014 grams per cubic centimeter. If the earth’s density were equal to the average nuclear density, the earth’s radius would be only about 200 meters.
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素稳定型基乙烯

Kilian M Krebs1, Dominik Hanselmann1, Hartmut Schubert1

  • 1Institut für Anorganische Chemie , Eberhard Karls Universität Tübingen , Auf der Morgenstelle 18 , 72076 Tübingen , Germany.

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|February 9, 2019
PubMed
概括

研究人员从素-素易斯对和二中合成了一种新型的稳定型维尼利丁. 这种化合物经历 [2+2] 循环添加,可以转移原子,形成有机化.

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科学领域:

  • 有机金属化学
  • 主要组化学
  • 无机合成

背景情况:

  • 基素易斯对是一种反应性中间体.
  • 稳定的低价值化合物具有显著的兴趣.
  • 了解细菌素的反应性对于开发基于的新材料至关重要.

研究的目的:

  • 合成和描述一种新型的素稳定型基乙烯.
  • 为了研究其电子结构.
  • 在循环添加和原子抽象反应中探索除乙烯的反应性.

主要方法:

  • 一个分子内基素易斯对与二二的反应.
  • 使用或来减少由替代的细菌添加物.
  • 使用X射线结晶学,密度函数理论 (DFT) 计算和与阿达曼基因和阿达曼胺的反应进行了表征.

主要成果:

  • 在92%的产量中合成替代体的素添加物.
  • 素稳定型乙烯的分离在72%的产量 (Mg减少) 或52%的产量 (Na减少).
  • 一个 [2+2] 循环添加产品与阿达曼酸和一个四重体有机酸与阿达曼酸的特征.

结论:

  • 一种新型的素稳定型乙烯已成功合成和表征.
  • 迪格马维尼利丁具有独特的反应性,参与循环添加和原子抽象反应.
  • DFT计算提供了关于这种化合物的电子结构的见解.