KLi(HC3N3O3) ·2H2O:溶剂滴研磨方法向水分异酸盐非线性光学晶体
Donghong Lin1,2, Min Luo1, Chensheng Lin1
1Key Laboratory of Optoelectronic Materials Chemistry and Physics , Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences , Fuzhou , Fujian 350002 , China.
Journal of the American Chemical Society
|February 13, 2019
概括
合成了一种新型的化水性异酸盐晶体,KLi(HC3N3O3) ·2H2O. 这种材料具有出色的非线性光学特性,包括高的二次波生成响应和激光损伤值,使其对激光应用具有前景.
科学领域:
- 材料科学
- 固态化学
- 晶体学
背景情况:
- 非线性光学 (NLO) 材料对于激光技术至关重要.
- 开发具有增强性能和改进可加工性的新型NLO晶体是一个正在进行的研究领域.
- 化酸盐的混合金属盐为新型NLO应用提供了潜力.
研究的目的:
- 合成和表征一种新的混合化水化合物晶体.
- 评估新材料的非线性光学特性.
- 探索大量单晶的实际应用的可行性.
主要方法:
- 用于结晶合成的溶剂滴磨法.
- 用于散装单晶生长的水溶液技术
- 使用技术来确定光学和物理性质的表征.
主要成果:
- 成功合成KLi(HC3N3O3) ·2H2O.
- 观察到大的第二波反应 (SHG) (5.3 × KH2PO4).
- 达到237纳米的紫外线 (UV) 切断边.
- 容易生长的散装单晶.
- 高激光损伤值 (LDT) 为4.76GW/cm2.
- 较大的双折射 (Δn = 0.186@514 nm).
- 将I型相匹配波长缩短到246 nm.
结论:
- KLi ((HC3N3O3) ·2H2O是一种有前途的新型非线性光学材料.
- 这种晶体具有优良的NLO特性和良好的可加工性.
- 它的性能表明在先进的激光系统和频率转换技术中的潜在应用.
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