3d-金属诱导磁性排序在U(IV) 原子上作为通往U(IV) 磁性材料的途径
Vladislav V Klepov1, Kristen A Pace1, Stuart Calder2
1Department of Chemistry and Biochemistry , University of South Carolina , Columbia , South Carolina 29208 , United States.
Journal of the American Chemical Society
|February 14, 2019
概括
研究人员通过添加3D过渡金属在中实现了磁性排序. 这创造了新的U(IV) 铁磁材料,抑制了典型的二磁基态,并使其具有新的磁性.
科学领域:
- 固态化学
- 磁性
- 材料科学
背景情况:
- 在低温下, (IV) 5f2磁性通常会从三重体转变为单重体的基本状态.
- 控制的磁性基本状态对于开发先进的磁性材料至关重要.
研究的目的:
- 在复杂化物中实现原子的磁性排序.
- 合成和描述一系列新的铁磁材料.
- 研究三维过渡金属对磁性的作用.
主要方法:
- 新型Cs2MU3F16化合物的合成 (M = Mn2+,Co2+,Ni2+).
- 测量磁性易感性以确定磁性相位过渡.
- 为了阐明磁体结构和瞬间,
主要成果:
- 成功合成了前所未有的U (IV) 铁磁材料:Cs2MU3F16.
- 对M = Mn2+,Co2+,Ni2+的低温度 (4.0-14.0 K) 的铁磁性相变的观察.
- 中子衍射证实了U磁矩 (0.91-1.97μB) 和反平行3d矩 (1.53-3.26μB).
结论:
- 通过3d-5f交换合,将3d过渡金属纳入中诱导磁性排序.
- 合成的材料抑制了U的特征性二磁性基本状态.
- 这项工作为设计基于的磁性材料开辟了新的途径.
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