作为高硫电池的单原子催化剂,在添加的石墨烯中
Zhenzhen Du1, Xingjia Chen, Wei Hu
1School of Chemistry and Chemical Engineering , Hefei University of Technology , Hefei 230009 , China.
Journal of the American Chemical Society
|February 16, 2019
概括
用添加的石墨烯中的单分散原子作为硫电池的双功能催化剂. 这提高了电化学性能,促进了可逆聚硫化物转化,以有效储存能量.
科学领域:
- 材料科学
- 电化学
- 催化剂
背景情况:
- -硫 (Li-S) 电池具有较高的理论能量密度和较低的成本.
- 有效的可逆转换聚硫化物对于Li-S电池的性能至关重要.
研究的目的:
- 研究嵌入在配合石墨烯 (Co-N/G) 中的单分散原子作为Li-S电池的催化剂.
- 阐明聚硫化物转换中的Co-N-C协调中心的催化机制.
主要方法:
- 进行X射线吸收光谱.
- 基本原则的计算.
- 合成高硫度的S@Co-N/G复合物
主要成果:
- Co-N/G作为一个双功能电催化剂,促进Li2S的形成 (放电) 和分解 (电荷).
- 该S@Co-N/G复合物 (90重%S) 的重力容量为1210mAhg-1.
- 在0.2°C的100个循环中显示了5.1 mAh cm-2的面积容量和低色率 (每循环0.029%).
结论:
- Co-N/G是提高Li-S电池电化学性能的有效催化剂.
- Co-N-C协调中心在多硫化物表面中介反应中起着关键作用.
- 这种复合材料对下一代储能设备具有前景.
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