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Network Covalent Solids02:18

Network Covalent Solids

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Network covalent solids contain a three-dimensional network of covalently bonded atoms as found in the crystal structures of nonmetals like diamond, graphite, silicon, and some covalent compounds, such as silicon dioxide (sand) and silicon carbide (carborundum, the abrasive on sandpaper). Many minerals have networks of covalent bonds.
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When two atoms share electrons to complete their valence shells, they create a covalent bond. An atom's electronegativity—the force with which shared electrons are pulled towards an atom—determines how the electrons are shared. Molecules formed with covalent bonds can be either polar or nonpolar. Atoms with similar electronegativities form nonpolar covalent bonds; the electrons are shared equally. Atoms with different electronegativities share electrons unequally,...
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Unlike ionic or small covalent molecules, polymers do not form crystalline solids due to the diffusion limitations of their long-chain structures. However, polymers contain microscopic crystalline domains separated by amorphous domains.
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基于的结晶共价有机框架

Jian-Xin Ma1,2, Jian Li3, Yi-Fan Chen4

  • 1Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Molecular Recognition and Function, Institute of Chemistry, Chinese Academy of Sciences , Beijing 100190 , China.

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|February 19, 2019
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概括

研究人员开发了基于的新型结晶共价有机框架 (COF),具有永久透性,用于二氧化碳吸附. 这些独特的结构是二维和三维COF的桥梁,将多孔的有机与延伸的框架合并.

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科学领域:

  • 材料科学
  • 超分子化学
  • 纳米技术

背景情况:

  • 共价有机框架 (COF) 是具有可调节结构的晶体多孔聚合物.
  • 开发新的COF架构对于先进的材料应用至关重要.
  • 通过弥合多孔有机和扩展框架, 提供了新的设计可能性.

研究的目的:

  • 构建基于的新型结晶共价有机框架 (COF).
  • 研究合成的子COF的结构特征和多孔性.
  • 评估这些新材料的二氧化碳吸附能力.

主要方法:

  • 使用像镜的分子子和二胺链接剂合成-COF-1和-COF-2.
  • 使用13C CP/MAS NMR等技术进行结构性表征.
  • 孔径和气体吸附测量,重点是二氧化碳吸收.

主要成果:

  • 通过六角骨架成功合成了两种新的基于的COF (COF-1和COF-2).
  • 这种独特的结构具有柱状结和悬挂连接器, 形成三角道和相互连接的孔隙.
  • 子COF具有永久的多孔性,并通过子内腔促进有效的二氧化碳吸附.

结论:

  • 新型COF结合了2D和3DCOF的特征,弥合了多孔有机和扩展的晶体有机框架.
  • 这些材料具有永久性多孔性,并显示出捕获二氧化碳的应用潜力.
  • 该研究引入了一类具有独特结构和功能特性的COF.