化实现 抗矿 分子铁电 在 [(CH3) 2(F-CH2CH2) NH]3
Zhong-Xia Wang1,2, Yi Zhang2, Yuan-Yuan Tang1
1Ordered Matter Science Research Center , Nanchang University , Nanchang 330031 , People's Republic of China.
Journal of the American Chemical Society
|February 26, 2019
概括
研究人员开发了一种新的有机-无机混合抗矿铁电材料. 化策略成功地改变了结构,产生了增强的铁电特性和高和极化.
科学领域:
- 材料科学
- 固态化学
- 晶体学
背景情况:
- 抗矿是一种具有不同物理性质的功能性材料.
- 在无机陶中发现反矿铁电是罕见的.
- 分子设计是开发新功能材料的关键策略.
研究的目的:
- 报告一个新的有机-无机混合抗矿铁电.
- 研究分子设计和化对结构和铁电特性的影响.
- 提供一种用于设计反矿铁电的新战略.
主要方法:
- 涉及乙基替代和化的分子设计.
- 结构分析以确认矿转化为反矿.
- 铁电性能测量包括介电过渡,SHG,歇斯底里循环和域成像.
主要成果:
- 合成了一种新的有机-无机杂交反矿铁电: [{CH3) 2{F-CH2CH2) NH] 3{CdCl3) {CdCl4}.
- 化诱导的结构转变从非极性矿到极性反矿.
- 观察到室温以上的铁电相变 (Tc = 333 K) 具有显著的介电和光学反应.
- 达到4.0μC/cm2的高和极化 (Ps),大约是之前报告的反矿分子铁电的10倍.
- 证明了低强制场和容易的偏振切换.
结论:
- 化是有机-无机混合材料结构转换和性能调整的有效策略.
- 发现的反矿具有潜在应用的有前途性质.
- 这项工作为设计和探索新型反矿有机-无机混合铁电材料开辟了新的途径.
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