基于阴离子的结构调整和对它们自组装的形态控制
Huacheng Zhang1,2, Juhoon Lee2, James T Brewster2
1School of Chemical Engineering and Technology , Xi'an Jiaotong University , Xi'an , Shaanxi 710049 , China.
Journal of the American Chemical Society
|March 1, 2019
概括
研究人员通过改变对子离子来控制二烯酸盐和聚合物的形成. 这种基于阴离子的调节提供了一种控制自组合无机材料形态的新方法.
科学领域:
- 超分子化学
- 材料科学
- 协调化学
背景情况:
- 二烯酸是一种自组装的无机材料,在各种领域都有潜在的应用.
- 控制这些子及其更高层次结构的制造对于定制它们的特性至关重要.
- 之前的研究表明,反可以影响这些的结构,其中一些位于腔内.
研究的目的:
- 研究不同反子对二酸盐的自我组装的影响.
- 探索基于子的二元体,聚合物和更高阶组合的形成.
- 通过基离子控制建立一种新的微调自组合无机材料的多维形态方法.
主要方法:
- 使用两个起始材料:一个角联体和乙酸 (Zn) 2.
- 改变反源以指导自组装过程.
- 通过使用适当的分析技术来描述产生的结构和聚合物材料.
主要成果:
- 通过改变对子离子来控制制造不同的二烯酸 (Cage-3,Cage-5) 和聚合物材料 (PC-1,PC-2).
- 证明了反 (例如,四甲基,二甲基,四甲基,二甲基) 可以在外存在或影响的组装.
- 证明有机能调节单个子的进一步组装,导致更高层次的组合.
结论:
- 酸在电荷平衡和二烯酸盐和聚合物结构调整中起着双重作用.
- 基于阴离子的调为控制自组合无机材料的多维形态提供了一种新且有效的策略.
- 这种方法可以为潜在的应用微调超分子架构.
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