基于三基的螺旋形几何结构的梯形聚合物
Tomoyuki Ikai1,2, Takumu Yoshida1, Ken-Ichi Shinohara3
1Graduate School of Natural Science and Technology , Kanazawa University , Kakuma-machi , Kanazawa 920-1192 , Japan.
Journal of the American Chemical Society
|March 1, 2019
概括
研究人员使用分子内循环合成了光学活跃的梯子聚合物. 这种方法创造了精确的螺旋结构,为新奇的手术材料铺平了道路.
科学领域:
- 有机化学
- 聚合物科学
- 材料科学
背景情况:
- 基质分子和聚合物对于先进材料至关重要.
- 开发复杂的合结构的高效合成路径仍然是一个挑战.
研究的目的:
- 报告光学活性梯子类分子和聚合物的高效合成.
- 探索纳米级螺旋结构的构建.
主要方法:
- 含有特定的基乙单元的奇拉三基的分子内循环.
- 由硬质因子指导的电友诱导的循环反应.
主要成果:
- 在没有副产品的情况下实现了光学活性梯子单元的高效合成.
- 生产的聚合物具有明确的单手螺旋几何和螺旋排列的二[a,h]炭单元.
- 已经证明了量化和区域选择性循环.
结论:
- 开发的合成路径可以创建多种纳米级螺旋梯架构.
- 这项工作为新奇的手术材料提供了新的途径.
- 这种方法可以精确地控制聚合物中的螺旋形状.
相关概念视频
Polymers
40.7K
The word polymer is derived from the Greek words “poly” which means “many” and “mer” which means “parts”. Polymers are long chains of molecules composed of repeating units of smaller molecules, known as monomers. They either occur naturally, such as DNA and proteins, or can be constructed synthetically, like plastics. They have varied structural characteristics, such as linear chains, branched chains, or complex networks, that contribute to the...
40.7K
Coordination Number and Geometry
19.0K
For transition metal complexes, the coordination number determines the geometry around the central metal ion. Table 1 compares coordination numbers to molecular geometry. The most common structures of the complexes in coordination compounds are octahedral, tetrahedral, and square planar.
19.0K
Predicting Molecular Geometry
45.7K
VSEPR Theory for Determination of Electron Pair Geometries
45.7K
Ladder Diagrams: Acid–Base Equilibria
1.8K
Understanding the chemistry between the reagents is necessary for performing any experiment. To this end, scientists have designed a tool called a ladder diagram, which is a graphical representation that helps illustrate the chemistry of a system.
A ladder diagram for acid-base equilibria consists of a vertical axis that represents pH and horizontal bars (steps on the ladder) that help position all the pKa values in the system. At equilibrium, the pH value of the system corresponds to one of...
A ladder diagram for acid-base equilibria consists of a vertical axis that represents pH and horizontal bars (steps on the ladder) that help position all the pKa values in the system. At equilibrium, the pH value of the system corresponds to one of...
1.8K
Geometry of Hyperbolas
492
A hyperbola consists of all points where the absolute difference of distances to two fixed points, called foci, remains constant. The standard equation isEach branch extends infinitely and approaches two asymptotes, which guide the curve’s behavior. The parameters a and b define key features: a measures the distance from the center to each vertex along the transverse axis, while b influences the slopes of the asymptotes. The asymptotes have equationsA rectangle centered at the origin with...
492
Ladder Diagrams: Complexation Equilibria
627
Ladder diagrams are useful for evaluating equilibria involving metal-ligand complexes. The vertical scale of the ladder diagram represents the concentration of unreacted or free ligand, pL. The horizontal lines on the scale depict the log of stepwise formation constants for metal-ligand complexes and indicate the dominant species in all the regions.
The formation constant, K1, for the formation of Cd(NH3)2+ complex from cadmium and ammonia is 3.55 × 102. Log K1 (i.e. pNH3) is 2.55, and...
The formation constant, K1, for the formation of Cd(NH3)2+ complex from cadmium and ammonia is 3.55 × 102. Log K1 (i.e. pNH3) is 2.55, and...
627


