Co2+-链接[NaP5W30O110]14-:具有高电子密度的反氧活性金属氧化物框架
Michael J Turo1, Linfeng Chen1, Curtis E Moore1
1Department of Chemistry and Biochemistry , University of California, San Diego , La Jolla , California 92093 , United States.
Journal of the American Chemical Society
|March 5, 2019
概括
研究人员开发了一种新型的金属氧化物框架, 这一发现有助于设计具有可调节电子特性的先进材料.
科学领域:
- 材料科学
- 无机化学
- 电化学
背景情况:
- 金属氧化物框架提供可调节的电子特性.
- 聚氧甲酸盐是多功能分子构建块.
- 在扩展固体中储存电子对于能源应用至关重要.
研究的目的:
- 合成和描述基于普雷斯勒离子的新金属氧化物框架.
- 研究该框架的光化学还原和电子存储能力.
- 探索电子添加对材料导电性和结构的影响.
主要方法:
- 使用普雷斯勒离子和离子合成金属氧化物框架.
- 用光化学还原实验来诱导电子储存.
- 用分子物种进行定,以评估可逆性和容量.
- 导电性测量以评估电子性能.
主要成果:
- 由氧化还原活性普雷斯勒离子和Co ((H2O) 42+单元形成的新型框架已成功合成.
- 框架显示可逆光化学减少,在温和条件下存储每团10个电子.
- 在没有结构变化的电子移位后观察到导电率显著增加1000倍.
- 在该框架内实现了高电子密度 (10^21 cm^-3).
结论:
- 这项研究证明了将移位电子存储成功纳入自组装的扩展固体.
- 这项工作为开发和调整具有增强电子性能的金属氧化物材料铺平了道路.
- 这些发现突显了基于聚氧甲的框架在先进电子和储能应用中的潜力.
更多相关视频
14:58Silicon Metal-oxide-semiconductor Quantum Dots for Single-electron Pumping
Published on: June 3, 2015
15.4K
11:04Ion Mobility-Mass Spectrometry Techniques for Determining the Structure and Mechanisms of Metal Ion Recognition and Redox Activity of Metal Binding Oligopeptides
Published on: September 7, 2019
9.8K
相关概念视频
Balancing Redox Equations
61.9K
Electrochemistry is the science involved in the interconversion of electrical and chemical reactions. Such reactions are called reduction-oxidation, or redox reactions. These important reactions are defined by changes in oxidation states for one or more reactant elements and include a subset of reactions involving the transfer of electrons between reactant species. Electrochemistry as a field has evolved to yield sufficient insights on the fundamental principles of redox chemistry and multiple...
61.9K
Oxidation Numbers
42.5K
In redox reactions, the transfer of electrons occurs between reacting species. Electron transfer is described by a hypothetical number called the oxidation number (or oxidation state). It represents the effective charge of an atom or element, which is assigned using a set of rules.
42.5K
Redox Reactions
58.7K
Oxidation-reduction or redox reactions involve the transfer of electrons from one molecule or atom to another. When an atom gains an electron, another atom must lose an electron, meaning oxidation and reduction must occur together. Since the redox occurs in pairs, the atom that gets oxidized is also called the reducing agent or reductant, and the atom that is reduced is also called the oxidizing agent or oxidant. A straightforward way to remember the definitions of oxidation and reduction is...
58.7K
Oxidation-Reduction Reactions
75.5K
Oxidation–Reduction Reactions
75.5K
Redox Titration: Other Oxidizing and Reducing Agents
1.4K
Besides iodine, other oxidizing or reducing agents can serve as titrants in redox titrations. Common oxidizing titrants include KMnO4, cerium(IV), and K2Cr2O7. The choice of oxidizing titrants depends on factors like stability, cost, analyte strength, and reaction rate between the analyte and titrant. KMnO4 is a strong oxidizing titrant that reduces from Mn(VII) to Mn(II) in a highly acidic solution, simultaneously oxidizing the analyte to a higher oxidation state. In this case, KMnO4 acts as a...
1.4K
Electron Carriers
91.7K
Electron carriers can be thought of as electron shuttles. These compounds can easily accept electrons (i.e., be reduced) or lose them (i.e., be oxidized). They play an essential role in energy production because cellular respiration is contingent on the flow of electrons.
Over the many stages of cellular respiration, glucose breaks down into carbon dioxide and water. Electron carriers pick up electrons lost by glucose in these reactions, temporarily storing and releasing them into the electron...
Over the many stages of cellular respiration, glucose breaks down into carbon dioxide and water. Electron carriers pick up electrons lost by glucose in these reactions, temporarily storing and releasing them into the electron...
91.7K
