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由分子内结相互作用促进的血--铜复合物的自旋互转

Andrew W Schaefer1, Melanie A Ehudin2, David A Quist2

  • 1Department of Chemistry , Stanford University , Stanford , California 94305 , United States.

Journal of the American Chemical Society
|March 6, 2019
PubMed
概括

具有结能力的合成桥复合物表现出可逆自旋交叉 (SCO). 分子内H键稳定低旋转状态,影响电子结构并使温度依赖的旋转状态相互转换.

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