五角
Dong Meng1,2, Guogang Liu2,3, Chengyi Xiao4
1Key Laboratory of Organic Optoelectronics and Molecular Engineering, Department of Chemistry , Tsinghua University , Beijing 100084 , China.
Journal of the American Chemical Society
|March 9, 2019
概括
研究人员使用二胺 (PDI) 碎片和二烯核合成了一种新型非平面石墨烯,即二烯五角 (CRP). D5对称结构显示了通过其独特的蜂晶格传输电子的潜力.
科学领域:
- 材料科学
- 有机化学
- 纳米技术
背景情况:
- 在合成非平面石墨烯方面取得了重大进展.
- 在理解结构-特性关系,特别是分子间相互作用方面仍然存在挑战.
研究的目的:
- 呈现一个新的非平面图形体,Coranurylene pentapetalae (CRP).
- 研究CRP的结构特征和分子间相互作用.
- 探索CRP在电子设备中的潜力.
主要方法:
- 由底向上合成,涉及二胺 (PDI) 平面碎片和曲核心.
- 单晶X射线衍射用于结构阐明.
- 晶体管设备的制造和测试
主要成果:
- 确定了两个不同的CRP结构:D5对称和C2对称.
- D5对称的CRP表现出一个独特的,交替堆叠的状蜂巢格子.
- 通过π-π堆叠,C2对称的CRP形成了二元单元.
- 晶体管装置显示,D5对称的CRP的蜂晶格甚至在没有π-π堆叠的情况下也能促进电子传输.
结论:
- 角烯五 (CRP) 是一种新型的非平面石墨烯类.
- 在电子传输应用中,D5对称的CRP的蜂结构具有前景.
- 这项工作有助于理解复杂的石墨烯体中的结构-属性关系.
相关概念视频
Nomenclature of Alkenes
The IUPAC naming system for alkenes replaces -an- with -en- in the corresponding parent alkanes. Accordingly, a simple alkene replaces the -ane suffix of the alkane with -ene.
As per the IUPAC rules, the longest carbon chain containing the maximum number of double bonds is identified as the parent chain and is numbered such that the doubly bonded carbon atoms receive the lowest possible numbers. The location of the double bond is indicated by the number of its first carbon atom. In branched...
As per the IUPAC rules, the longest carbon chain containing the maximum number of double bonds is identified as the parent chain and is numbered such that the doubly bonded carbon atoms receive the lowest possible numbers. The location of the double bond is indicated by the number of its first carbon atom. In branched...
Nomenclature of Alkynes
Alkynes are unsaturated hydrocarbons characterized by the presence of carbon-carbon triple bonds and have a general formula CnH2n-2. The nomenclature of alkynes follows a set of rules similar to alkanes and alkenes; however, alkynes bear the suffix "-yne" instead of "-ane" or "-ene." There are two approaches to naming alkynes:
Structure of Conjugated Dienes
Introduction
Conjugated dienes are compounds characterized by the presence of alternating double and single bonds. In a conjugated system like 1,3-butadiene, the unhybridized 2p orbital on each carbon overlaps continuously, allowing the π electrons to be delocalized across the entire molecule. In contrast, this type of overlap does not occur in cumulated and isolated dienes, such as 2,3-pentadiene and 1,4-pentadiene, respectively. Instead, the π electrons remain localized between the double...
Conjugated dienes are compounds characterized by the presence of alternating double and single bonds. In a conjugated system like 1,3-butadiene, the unhybridized 2p orbital on each carbon overlaps continuously, allowing the π electrons to be delocalized across the entire molecule. In contrast, this type of overlap does not occur in cumulated and isolated dienes, such as 2,3-pentadiene and 1,4-pentadiene, respectively. Instead, the π electrons remain localized between the double...
Aromatic Hydrocarbon Anions: Structural Overview
Neutral hydrocarbons like cyclopentadiene with an odd number of carbon atoms and one intervening CH2 group in the ring are not aromatic. Cyclopentadiene with 4 π electrons does not satisfy the 4n + 2 π electron rule. Additionally, the intervening CH2 group is sp3 hybridized and lacks a vacant p orbital, thereby interrupting the overlap of p orbitals in a continuous manner and preventing the delocalization of π electrons throughout the ring.
Due to the absence of continuous overlap of p...
Due to the absence of continuous overlap of p...
Aryldiazonium Salts to Azo Dyes: Diazo Coupling
The reaction of weakly electrophilic aryldiazonium (also called arenediazonium) salts with highly activated aromatic compounds leads to the formation of products with an —N=N— link, called an azo linkage. This reaction, presented in Figure 1, is known as diazo coupling and occurs without the loss of the nitrogen atoms of the aryldiazonium salt. Highly activated aromatic compounds such as phenols or arylamines favor the diazo coupling reaction. The coupling generally occurs at the para position.
Characteristics and Nomenclature of Copolymers
Copolymers are the products obtained from the polymerization of multiple monomer species. So, in a polymer chain itself, there can be multiple repeating units that come from different monomers. The process of synthesizing a polymer from different monomer species is called copolymerization. When two monomers are involved, the polymer is known as a bipolymer. Polymers with three and four monomers are termed terpolymers and quaterpolymers, respectively. Figure 1 depicts the copolymerization of...


