铁磁范德瓦尔斯晶体VI
Shangjie Tian1, Jian-Feng Zhang1, Chenghe Li1
1Department of Physics and Beijing Key Laboratory of Optoelectronic Functional Materials & Micro-Nano Devices , Renmin University of China , Beijing 100872 , P. R. China.
Journal of the American Chemical Society
|March 12, 2019
概括
三 (VI3) 晶体在79K时呈现结构转变,在50K以下变得铁磁.这种范德瓦尔斯材料是二维铁磁半导体的有希望的候选材料.
科学领域:
- 凝聚物质物理学
- 材料科学
- 固态化学
背景情况:
- 范德瓦尔斯 (vdW) 晶体对于探索新的电子和磁性特性至关重要.
- 了解VDW材料的结构,磁性和电子行为之间的相互作用是技术进步的关键.
研究的目的:
- 研究VDW晶体VI3的结构,物理和电子特性.
- 确定VI3作为二维 (2D) 铁磁半导体的潜力.
主要方法:
- 结构和物理性质的实验性表征.
- 理论计算以确定电子结构和频段间隙.
- 对磁过渡和局部瞬间行为的分析.
主要成果:
- 在大约79K时,VI3的结构从单临床转变为面.
- 远程铁磁过渡发生在50K以下,V时刻接近高旋转V3+状态 (S=1).
- 理论计算表明,VI3是一种Mott绝缘体,带间隙为0.90 eV,具有较低的层间结合能,使其能够脱皮.
结论:
- 由于其结构和磁性特性,VI3是二维铁磁半导体的有希望的候选材料.
- 它为研究S=1系统中的二维磁性和vdW异构结构提供了一个新的平台.
相关概念视频
Van der Waals Interactions
71.2K
Atoms and molecules interact with each other through intermolecular forces. These electrostatic forces arise from attractive or repulsive interactions between particles with permanent, partial, or temporary charges. The intermolecular forces between neutral atoms and molecules are ion–dipole, dipole–dipole, and dispersion forces, collectively known as van der Waals forces.
71.2K
Van der Waals Equation
6.3K
The ideal gas law is an approximation that works well at high temperatures and low pressures. The van der Waals equation of state (named after the Dutch physicist Johannes van der Waals, 1837−1923) improves it by considering two factors.
First, the attractive forces between molecules, which are stronger at higher densities and reduce the pressure, are considered by adding to the pressure a term equal to the square of the molar density multiplied by a positive coefficient a. Second, the volume...
First, the attractive forces between molecules, which are stronger at higher densities and reduce the pressure, are considered by adding to the pressure a term equal to the square of the molar density multiplied by a positive coefficient a. Second, the volume...
6.3K
Real Gases: Effects of Intermolecular Forces and Molecular Volume Deriving Van der Waals Equation
39.0K
Thus far, the ideal gas law, PV = nRT, has been applied to a variety of different types of problems, ranging from reaction stoichiometry and empirical and molecular formula problems to determining the density and molar mass of a gas. However, the behavior of a gas is often non-ideal, meaning that the observed relationships between its pressure, volume, and temperature are not accurately described by the gas laws.
39.0K
Ferromagnetism
3.1K
Materials like iron, nickel, and cobalt consist of magnetic domains, within which the magnetic dipoles are arranged parallel to each other. The magnetic dipoles are rigidly aligned in the same direction within a domain by quantum mechanical coupling among the atoms. This coupling is so strong that even thermal agitation at room temperature cannot break it. The result is that each domain has a net dipole moment. However, some materials have weaker coupling, and are ferromagnetic at lower...
3.1K
Noncovalent Attractions in Biomolecules
64.7K
Noncovalent attractions are associations within and between molecules that influence the shape and structural stability of complexes. These interactions differ from covalent bonding in that they do not involve sharing of electrons.
Four types of noncovalent interactions are hydrogen bonds, van der Waals forces, ionic bonds, and hydrophobic interactions.
Hydrogen bonding results from the electrostatic attraction of a hydrogen atom covalently bonded to a strong-electronegative atom like oxygen,...
Four types of noncovalent interactions are hydrogen bonds, van der Waals forces, ionic bonds, and hydrophobic interactions.
Hydrogen bonding results from the electrostatic attraction of a hydrogen atom covalently bonded to a strong-electronegative atom like oxygen,...
64.7K
Van de Graaff Generator
2.4K
Van de Graaff generators (or Van de Graaffs) are devices used to demonstrate high voltage due to static electricity that can also be used for research. Robert Van de Graaff first built one in 1931 (based on original suggestions by Lord Kelvin) for use in nuclear physics research.
Van de Graaff uses both smooth and pointed surfaces, conductors, and insulators to generate large static charges and, hence, large voltages. A substantial excess charge can be deposited on the sphere because it moves...
Van de Graaff uses both smooth and pointed surfaces, conductors, and insulators to generate large static charges and, hence, large voltages. A substantial excess charge can be deposited on the sphere because it moves...
2.4K


