基于碳点支持的超分子组件的多色发光和纯白光发射的现场光转换
Huang Wu1,2, Yong Chen1, Xianyin Dai1
1College of Chemistry, State Key Laboratory of Elemento-Organic Chemistry , Nankai University , 94 Weijin Road , Nankai District, Tianjin 300071 , P.R. China.
Journal of the American Chemical Society
|March 13, 2019
概括
研究人员开发了一种用于多色光发光的新型超分子组件. 这种材料可以在现场进行光控制的色彩转换,从而使先进的应用实现可调光发射.
科学领域:
- 材料科学
- 超分子化学
- 光物理学
背景情况:
- 开发具有外部刺激控制的多色光发光材料是一项挑战.
- 在现场光控制的多色发光输出是不常见的.
研究的目的:
- 描述一个光发光的超分子组合与现场光调宽频输出.
- 证明光强度和颜色转换的可逆光切换.
主要方法:
- 一个双阶段光发光的超分子组件的制备.
- 使用日利乙烯光切换和库库比特[8]uril宿主-客人复合.
- 有 anionic 碳点的三元超分子组件的形成
主要成果:
- 一个经过修饰的 styrylpyridinium diarylethene 客分子表现出可逆光控制的开/关.
- 复合黄[8]uril增强光强度,并允许可逆光诱导火/恢复.
- 三级组件显示有效的现场照相控制的颜色从黄色变为蓝色,使纯白光发射成为可能.
结论:
- 开发的超分子组件为光调节的多色光发光提供了一个新的平台.
- 这种方法为设计先进的防伪材料和视觉显示仪器提供了机会.
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