在氧化演化反应中的氧化催化剂的功能作用
Bae-Jung Kim1, Emiliana Fabbri1, Daniel F Abbott1
1Energy & Environment Division , Paul Scherrer Institut , Forschungstrasse 111 , 5232 Villigen PSI , Switzerland.
Journal of the American Chemical Society
|March 13, 2019
概括
铁 (Fe) 在 (Co) 基氧化物中增加氧化演化反应 (OER) 活性和性介质中的稳定性. 这项研究澄清了Fe
科学领域:
- 材料科学
- 电化学
- 催化剂
背景情况:
- 矿氧化物是性环境中氧化演化反应 (OER) 的有希望的催化剂.
- 基于的矿在B位点的部分铁 (Fe) 替代增强了活性和稳定性,但机制尚不清楚.
研究的目的:
- 阐明 (Co) 和铁 (Fe) 在立方矿的OER机制中的作用.
- 为了提高OER性能,研究Fe替代的矿的结构性质关系.
主要方法:
- 通过火焰喷雾合成合成La0.2Sr0.8Co1-xFe_xO3-δ和Ba0.5Sr0.5Co1-xFe_xO3-δ (x=0,0.2) 的纳米粒子.
- 现场和操作式X射线吸收光谱 (XAS) 用于分析局部电子和几何结构.
- 密度函数理论 (DFT) 计算用于理论见解.
主要成果:
- 铁的加入改变了基矿的内在性质.
- 在物理化学特性和电化学性能之间确立了明确的关系.
- 用铁替代的矿具有高效的OER活性和增强的稳定性.
结论:
- 铁在增强基于的矿催化剂的活性和稳定性方面起着至关重要的作用.
- 这些发现更深入地了解了Fe对这些材料的OER机制的贡献.
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