通过有机的化在二维矿中增强电荷传输
Fei Zhang1, Dong Hoe Kim1, Haipeng Lu1
1National Renewable Energy Laboratory , Golden , Colorado 80401 , United States.
Journal of the American Chemical Society
|March 19, 2019
概括
在二维矿的有机间隔剂中使用替代可以提高矿太阳能电池的电荷传输和稳定性. 这种分子设计提高了新一代太阳能应用的效率和热性能.
科学领域:
- 材料科学
- 可再生能源
- 固态化学
背景情况:
- 二维 (2D) 有机-无机化矿为矿太阳能电池 (PSC) 提供了更好的稳定性.
- 在二维矿中体积大的间隔离子可以阻碍关键的电荷传输过程.
- 优化有机隔离器是释放二维矿全部潜力的关键.
研究的目的:
- 研究有机间隔器中的分子设计对二维矿的电荷传输的影响.
- 通过定制的有机组件提高矿太阳能电池的性能和稳定性.
- 探索替代作为提高二维矿性能的一种策略.
主要方法:
- 合成的4-甲 (F-PEA) 作为一种改性有机间隔剂.
- 使用简单的室温沉积方法制造的二维矿薄膜.
- 描述了由此产生的矿太阳能电池的结构,电子和稳定性.
主要成果:
- 在中的替代导致更短的环距离和更好的板对齐.
- 通过无机层观察到增强的轨道相互作用和电荷传输.
- 在基于 (F-PEA) 2MA4Pb5I16的PSC中实现了超过13%的功率转换效率.
- 与基于PEA的设备相比,显著改善了热稳定性.
结论:
- 有机间隔剂的分子工程,特别是通过替代,是一种有效的策略,以提高2D矿的电荷传输和载体寿命.
- 通过F-PEA改造,提高了二维矿太阳能电池的性能和热稳定性.
- 这种方法为开发高度稳定和高效的矿太阳能电池技术提供了有希望的途径.
相关概念视频
Ions and Ionic Charges
78.9K
In ordinary chemical reactions, the nucleus — which contains the protons and neutrons of each atom and thus identifies the element — remains unchanged. Electrons, however, can be added to atoms by transfer from other atoms, lost by transfer to other atoms, or shared with other atoms. The transfer and sharing of electrons among atoms govern the chemistry of the elements. During the formation of some compounds, atoms gain or lose electrons to form electrically charged particles called...
78.9K
Formal Charges
40.3K
In some cases, there are seemingly more than one valid Lewis structures for molecules and polyatomic ions. The concept of formal charges can be used to help predict the most appropriate Lewis structure when more than one reasonable structure exists.
40.3K
Facilitated Transport
147.5K
The chemical and physical properties of plasma membranes cause them to be selectively permeable. Since plasma membranes have both hydrophobic and hydrophilic regions, substances need to be able to transverse both regions. The hydrophobic area of membranes repels substances such as charged ions. Therefore, such substances need special membrane proteins to cross a membrane successfully. In facilitated transport, also known as facilitated diffusion, molecules and ions travel across a...
147.5K
Secondary Active Transport
137.7K
One example of how cells use the energy contained in electrochemical gradients is demonstrated by glucose transport into cells. The ion vital to this process is sodium (Na+), which is typically present in higher concentrations extracellularly than in the cytosol. Such a concentration difference is due, in part, to the action of an enzyme “pump” embedded in the cellular membrane that actively expels Na+ from a cell. Importantly, as this pump contributes to the high concentration of...
137.7K
Short-distance Transport of Resources
17.6K
Short-distance transport refers to transport that occurs over a distance of just 2-3 cells, crossing the plasma membrane in the process. Small uncharged molecules, such as oxygen, carbon dioxide, and water, can diffuse across the plasma membrane on their own. In contrast, ions and larger molecules require the assistance of transport proteins due to their charge or size. Transport across membranes also occurs within individual cells, playing a variety of essential roles for the plant as a whole.
17.6K
Atomic Radii and Effective Nuclear Charge
61.9K
The elements in groups of the periodic table exhibit similar chemical behavior. This similarity occurs because the members of a group have the same number and distribution of electrons in their valence shells.
61.9K


