通过气体介导的表面反应在微米尺度上合成高度规律的单层基银网络
Yi-Qi Zhang1, Tobias Paintner1, Raphael Hellwig1
1Physics Department E20 , Technical University of Munich , D-85748 Garching , Germany.
Journal of the American Chemical Society
|March 20, 2019
概括
研究人员使用一种新的气体介导反应在银面上合成了扩展的有机金属银网络. 这种方法创造了有序的纳米孔状网络,在材料科学中具有潜在的应用.
科学领域:
- 表面科学
- 有机金属化学
- 材料科学
背景情况:
- 有机金属网络为高级应用提供可调节的特性.
- 表面介导合成可以控制纳米结构的形成.
- 银相互作用是构建扩展网络的关键.
研究的目的:
- 开发一种新的气体介导表面反应协议,用于合成扩展的有机金属银网络.
- 研究分子氧在脱质和网络形成过程中的作用.
- 描述由此产生的网络的结构性质和孔状特征.
主要方法:
- 在超高真空下在Ag{111) 表面上合成扩展的有机金属蜂网络.
- 使用气体介导的表面反应协议,涉及对分子氧的受控暴露.
- 1,3,5-tris ((4-乙烯) (Ext-TEB) 前体通过 O2 在 200 K 的解质.
- 轻度回火到375K以促进长距离有序网络的形成.
主要成果:
- 通过分子氧有效和化学选择性地去除终端基因部分的质子,而不会造成表面中毒.
- 包含基质银原子的长距离有序银网络的形成.
- 在网络中观察Ag-bis-acetylide图案和高结构质量.
- 创建一个规则的纳米孔排列,范德瓦尔斯腔约为8.3nm2.
结论:
- 通过O2介导的气体表面反应协议是合成扩展的有机金属银网络的可行方法.
- 合成的网络表现出具有纳米孔状特性的定义良好的结构.
- 这种方法可以精确地控制高贵金属表面的网络形成.
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