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适应矿太阳能电池中极小的开放电路电压损失的被动化分子结构
Shuang Yang1, Jun Dai, Zhenhua Yu1
1Department of Applied Physical Sciences , University of North Carolina , Chapel Hill , North Carolina 27599 , United States.
Journal of the American Chemical Society
|March 20, 2019
概括
研究人员设计了被动化分子来修复矿太阳能电池的缺陷. 这一策略提高了效率并减少了电压损失,指导了未来的性能设计.
科学领域:
- 材料科学
- 太阳能发电
- 固态化学
背景情况:
- 在矿太阳能电池中抑制电荷重组至关重要.
- 了解功能组的被动化机制对于优化设备性能至关重要.
- 现有的被动化策略缺乏关于不同分子群体如何与矿缺陷相互作用的清晰度.
研究的目的:
- 系统地研究矿材料上的各种功能组的被动化机制.
- 阐明工程分子与矿表面/粒度边界缺陷之间的相互作用.
- 设计用于高性能矿太阳能电池的新型被动化分子.
主要方法:
- 消极分子功能组 (碳基,氨基,异基,基,三基) 的系统工程.
- 对矿材料的被动化能力的评估.
- 对矿和被动化分子之间的相互作用进行分析.
- 一个新的被动化分子 (D-4-tert-butylphenylalanine) 的设计和合成.
主要成果:
- 通过静电相互作用治愈带电的缺陷.
- 芳香结构可以减少与中性有关的缺陷.
- 控制的分子相互作用使得谷物边界被动化,甚至在基板的深处.
- 一个新的分子D-4-tert-butylphenylalanine在p-i-n太阳能电池中实现了21.4%的稳定效率.
- 在1.57 eV的带隙矿中实现了0.34V的创纪录的低开通电压 (V_OC) 缺陷.
结论:
- 该研究阐明了基于功能组特性 (静电,芳香相互作用) 的被动化机制.
- 合理的分子设计使得有效的粒度边界被动化.
- 开发的分子和机械理解为先进的矿太阳能电池设计铺平了道路.
- 这些发现为创建各种矿电子应用的新被动化分子提供了指导.
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