电催化剂从表面安装的金属有机框架中获得的前所未有的高氧进化活动
Weijin Li1, Sebastian Watzele2,3, Hany A El-Sayed4
1Chair of Inorganic and Metal-organic Chemistry, Catalysis Research Center, Ernst-Otto-Fischer Straße 1 and Department of Chemistry , Technical University of Munich , Lichtenbergstraße 4 , 85748 Garching b. München , Germany.
Journal of the American Chemical Society
|March 20, 2019
概括
开发先进的电催化剂对于储存可再生能源至关重要. 这项研究介绍了来自SURMOF薄膜的新型混合/氧化电催化剂,显示出优异的氧化反应活性和稳定性.
科学领域:
- 电化学
- 材料科学
- 可再生能源
背景情况:
- 氧气演化反应 (OER) 对储能系统至关重要.
- 开发高效,耐用和可扩展的非贵金属OER电催化剂是一个重大挑战.
研究的目的:
- 合成和评估用于OER的新型氧化电催化剂.
- 研究表面安装金属有机框架 (SURMOF) 薄膜作为OER电催化剂的前体的潜力.
主要方法:
- 从电极基板上逐层增长的SURMOF薄膜中单步衍生混合/氧化物电催化剂.
- 在溶液中OER活性和稳定性的电化学特征.
- 分析催化剂形态和活性部位的暴露.
主要成果:
- 由此产生的混合/氧化电催化剂在性介质中具有较高的OER活性和稳定性.
- 在300 mV的超电位下达到2.5 mA·μg−1的质量活性,显著超过基准IrO2和最先进的催化剂.
- 来自SURMOF的超薄电催化剂涂层增加了活性Ni和Co位点的暴露.
结论:
- 由SURMOF衍生出的混合/氧化物是氧化演化反应的非常有前途的非贵金属电催化剂.
- 简单的合成和卓越的性能为先进的储能应用提供了可扩展的途径.
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